Cadmium(II) and zinc(II) azido complexes with different nuclearity and dimensionality

Franz A. Mautner; Christian Berger; Merlin J. Dartez; Quang L. Nguyen; Julien Favreau; Salah S. Massoud

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Cadmium(II) and zinc(II) azido complexes with different nuclearity and dimensionality

机译：具有不同核度和维数的镉（II）和锌（II）叠氮基络合物

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The reaction of Cd(ClO_4)_2·6H_2O with the tetradentate tripod amine BPQA (bis(2-methylpyridyl)-2-methylquinolyl- amine) afforded the mononuclear complex [Cd(BPQA)(N_3)_2] (1), whereas its reaction with the bidentate amines Et_2Meen (N,N-diethyl-N'-methylethylenediamine) and DMP (2-(3,5-dimethylpyrazol- 1-ylmethyl)pyridine) resulted in the formation of different bridged-azido polymeric 2D- and 1D-chains [Cd_2(Et_2Meen)_2(l1,1-N_3)_2(l1,3-N_3)_2]n (2) and [Cd(DMP)(l1,1-N_3)_2]n (3), respectively. The reaction of Zn(ClO_4)_2·6H_2O with DMP led to the isolation of the doubly bridged EO-azido dinuclear complex [Zn(DMP)(l1,1-N_3)(N_3)]_2 (4). The four complexes have been structurally characterized by elemental microanalyses, IR spectroscopy and by single crystal X-ray crystallography. The luminescence properties of [Cd(BPQA)(N_3)] (1) complex and its ligand, BPQA were investigated, where the complex revealed strong fluorescence enhancement.

机译：Cd（ClO_4）_2·6H_2O与四齿三脚胺BPQA（双（2-甲基吡啶基）-2-甲基喹啉基胺）反应生成单核络合物[Cd（BPQA）（N_3）_2]（1），与二齿胺Et_2Meen（N，N-二乙基-N'-甲基乙二胺）和DMP（2-（3,5-二甲基吡唑-1-基甲基）吡啶）的反应导致形成不同的桥叠氮基聚合物2D和1D -链[Cd_2（Et_2Meen）_2（l1,1-N_3）_2（l1,3-N_3）_2] n（2）和[Cd（DMP）（l1,1-N_3）_2] n（3）。 Zn（ClO_4）_2·6H_2O与DMP的反应导致双桥联的EO-叠氮基双核络合物[Zn（DMP）（1,1-N_3）（N_3）] _ 2（4）的分离。四种配合物的结构已经通过元素显微分析，红外光谱和单晶X射线晶体学进行了表征。研究了[Cd（BPQA）（N_3）]（1）配合物及其配体BPQA的发光特性，该配合物显示出较强的荧光增强作用。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2014年第null期|共7页
作者
Franz A. Mautner; Christian Berger; Merlin J. Dartez; Quang L. Nguyen; Julien Favreau; Salah S. Massoud;
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正文语种 eng
中图分类无机化学;
关键词
Cadmium; Zinc; Azido complexes; Polymeric complexes; Crystal structure; Fluorescence;

机译：镉;锌;叠氮基配合物;聚合物配合物;晶体结构;荧光;

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机译：对二甲苯二基和2-丁二基桥连二环的双核二聚镍（II），铜（II）和锌（II）配合物的合成和性质。

Cadmium(II) and zinc(II) azido complexes with different nuclearity and dimensionality

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