The synthesis and structure of trans-di(cyano-.KAPPA.1)-(trans-6,13-dimethyl-6,13-bis(propionylamido)-1,4,8,11-tetraazacyclotetradecane-.KAPPA.4)cobalt(III) perchlorate dihydrate

Curtis NF; Pawley R; Robinson WT

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >The synthesis and structure of trans-di(cyano-.KAPPA.1)-(trans-6,13-dimethyl-6,13-bis(propionylamido)-1,4,8,11-tetraazacyclotetradecane-.KAPPA.4)cobalt(III) perchlorate dihydrate

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The synthesis and structure of trans-di(cyano-.KAPPA.1)-(trans-6,13-dimethyl-6,13-bis(propionylamido)-1,4,8,11-tetraazacyclotetradecane-.KAPPA.4)cobalt(III) perchlorate dihydrate

机译：反式-二（氰基-.KAPPA.1）-（反式-6,13-二甲基-6,13-双（丙酰胺基）-1,4,8,11-四氮杂环十四烷-.KAPPA.4）的合成与结构高氯酸钴（III）二水合物

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trans-Di(cyano-kappa(1))-(trans-6,13-dimethyl-6,13-bis(propionylamicio) -1,4,8,11-tetraazacyclotetradecane-kappa(1))-cobalt(III) perchlorate dihydrate, trans-[Co(C18H38N6O2)(CN)(2))]ClO4 center dot 2H(2)O, is formed by reaction of trans-[Co(diam)(CN)(2)]ClO4 center dot 2H(2)O (diam=trans-6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecan e) with propionic anhydride in DMF. The centrosymmetrical cation has the azamacrocycle in planar coordination by the four secondary amine nitrogen atoms of the azamacrocycle, with Co-N = 1.979(2) and 1.968(2) angstrom and with trans cyano groups with Co-C = 1.920(2) angstrom. The propionylamido substituents are axially oriented, with the terminal methyl group disordered over two sites. 2008 Elsevier Ltd. All rights reserved.

机译：反式-二（氰基-kappa（1））-（反式-6,13-二甲基-6,13-双（丙酰酰胺基）-1,4,8,11-四氮杂环十四烷-kappa（1））-钴（III）高氯酸盐二水合物，通过反式-[Co（diam）（CN）（2）] ClO4中心点2H反应形成反式-[Co（C18H38N6O2）（CN）（2））] ClO4中心点2H（2）O （2）O（丙二酸=反式-6,13-二氨基-6,13-二甲基-1,4,8,11-四氮杂环十四烷e）在DMF中的丙酸酐。中心对称阳离子通过氮杂大环的四个仲胺氮原子在平面配位中具有氮杂大环，Co-N = 1.979（2）和1.968（2）埃，反式氰基的Co-C = 1.920（2）埃。丙酰胺基取代基是轴向取向的，末端甲基在两个位点上无序。 2008 Elsevier Ltd.保留所有权利。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2008年第13期|共3页
作者
Curtis NF; Pawley R; Robinson WT;
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正文语种 eng
中图分类化学;
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cobalt(III) compounds; cyclic tetraamine; azamacrocycle; amido-substitution; crystal structure; cyanide coordination; SUBSTITUTED CYCLIC TETRAAMINES; COBALT(III); TRANS-6; 13-DIAMINO-6; 13-DIMETHYL-1; 4; 8; 11-TETRAAZACYCLOTETRADECANE;

机译：钴（III）化合物;环四胺;氮杂双环;酰胺取代;晶体结构;氰化物配位;取代的环四胺;钴（III）;TRANS-6;13-DIAMINO-6;13-二甲基-1;4;8;11-四氮杂环丁烷;

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The synthesis and structure of trans-di(cyano-.KAPPA.1)-(trans-6,13-dimethyl-6,13-bis(propionylamido)-1,4,8,11-tetraazacyclotetradecane-.KAPPA.4)cobalt(III) perchlorate dihydrate

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