Syntheses, topological networks and properties of four complexes based on 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand

Xiang He; Jing-Jing Liu; Hong-Mei Guo; Min Shao; Ming-Xing Li

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Syntheses, topological networks and properties of four complexes based on 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand

机译：基于4-氨基-3,5-双（3-吡啶基）-1,2,4-三唑配体的四种配合物的合成，拓扑网络和性质

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Reactions of metal acetates with 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole (3-abpt) and co-ligands gave rise to four new complexes, namely [Zn2(3-abpt)(beta)(DMF) (H2O)2]nnH2O (1), [Zn(3-abpt)(ip)]n3nH2O (2), [Zn(3-abpt)(ip)(H2O)2]n2nH2O (3), and [Cu2(3-abpt)2(C6H5COO)4(H2O)2]n2nH2O (4) (ip = isophthalate, beta = 1,2,4,5-benzenetetracarboxylate). Compound 1 is a 3D coordination polymer with uncommon 3,4-connected (62.8)2(62.82.102) network. Compounds 2–4 are all 1D coordination polymers, which exhibit diversity structures. Compound 2 is a tubular-like chain, 3 is a ring-like network, and 4 is a zigzag chain. Their thermal stabilities and the photoluminescence of 1 have also been investigated.

机译：金属乙酸盐与4-氨基-3,5-双（3-吡啶基）-1,2,4-三唑（3-abpt）和共配体的反应产生了四个新的配合物，即[Zn2（3-abpt））β（DMF）（H2O）2] nnH2O（1），[Zn（3-abpt）（ip）] n3nH2O（2），[Zn（3-abpt）（ip）（H2O）2] n2nH2O（ 3）和[Cu2（3-abpt）2（C6H5COO）4（H2O）2] n2nH2O（4）（ip =间苯二甲酸，β= 1,2,4,5-苯四羧酸酯）。化合物1是3D配位聚合物，具有不常见的3,4-连接的（62.8）2（62.82.102）网络。化合物2-4均为一维配位聚合物，具有多样性的结构。化合物2是管状链，3是环状网络，4是曲折链。还研究了它们的热稳定性和1的光致发光。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2010年第3期|共7页
作者
Xiang He; Jing-Jing Liu; Hong-Mei Guo; Min Shao; Ming-Xing Li;
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正文语种 eng
中图分类无机化学;
关键词
4-Amino-3; 5-bis(3-pyridyl)-1; 2; 4-triazole; Coordination polymer; Crystal structure; Thermal analysis;

机译：4-氨基-3;5-双（3-吡啶基）-1;2;4-三唑;配位聚合物;晶体结构;热分析;

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1. Syntheses, topological networks and properties of four complexes based on 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand [J] . Xiang He, Jing-Jing Liu, Hong-Mei Guo, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第3期

机译：基于4-氨基-3,5-双（3-吡啶基）-1,2,4-三唑配体的四种配合物的合成，拓扑网络和性质
2. Syntheses, structures and thermal stabilities of four complexes with 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand [J] . Liu JJ, He X, Shao M, Journal of Molecular Structure . 2008,第1a3期

机译：4-氨基-3,5-双（3-吡啶基）-1,2,4-三唑配体的四种配合物的合成，结构和热稳定性
3. Metal- and anion-directed assemblies of Cu ~(II), Co ~(II), Ni ~(II), and Zn ~(II) coordination polymers based on a bent dipyridyl ligand 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole and malonic acid [J] . Jiang C.-H., Qi Y.-M., Sun Y., Journal of Molecular Structure . 2012,第Null期

机译：基于弯曲的二吡啶基配体4-氨基-3,5-双（）的Cu〜（II），Co〜（II），Ni〜（II）和Zn〜（II）配位聚合物的金属和阴离子定向组装体3-吡啶基）-1,2,4-三唑和丙二酸
4. Laser sensitive primary explosives: synthesis and properties of complexes with 3-hydrazino-4-amino-1,2,4-triazole (HATr) as ligand [C] . Cai-Xia Xu, Jian-Guo Zhang, XinYin Seminar on New Trends in Research of Energetic Materials . 2016

机译：对激光敏感的初级炸药：以3-肼基-4-氨基-1,2,4-三唑（HATr）为配体的配合物的合成和性质
5. Substitution chemistry of the cobalt complexes R carbon cobalt(3) nonacarbonyl (R = hydrogen, formyl radical) with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Syntheses, x-ray structures, and reactivity. [D] . Liu, Jie. 2001

机译：用二膦配体4,5-双（二苯基膦基）-4-环戊烯-1,3-二酮（bpcd）取代钴络合物R的碳（9）碳羰基钴（R =氢，甲酰基）：合成，x射线结构和反应性。
6. 4-Amino-3,5-dimethyl-4H-1,2,4-triazole [O] . Daojin Li, Guo-Chang Wei, Shu-Zhi Song, 2015

机译：4-氨基-3,5-二甲基-4H-1,2,4-三唑
7. Ruthenium(II) and osmium(II) polypyridyl complexes of an asymmetric pyrazinyl- and pyridinyl-containing 1,2,4-triazole based ligand. Connectivity and physical properties of mononuclear complexes [O] . Browne Wesley R., O’Connor Christine M., Hughes Helen P., 2002

机译：含不对称吡嗪基和吡啶基的1,2,4-三唑基配体的钌（II）和（II）多吡啶基配合物。单核配合物的连通性和物理性质

Syntheses, topological networks and properties of four complexes based on 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand

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