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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Synthesis, characterization and solubility studies of four new highly water soluble 1,3,5-triaza-7-phosphaadamantane (PTA) salts and their gold(I) complexes
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Synthesis, characterization and solubility studies of four new highly water soluble 1,3,5-triaza-7-phosphaadamantane (PTA) salts and their gold(I) complexes

机译：四种新型高水溶性1,3,5-三氮杂-7-磷金刚烷（PTA）盐及其金（I）配合物的合成，表征和溶解度研究

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摘要

The synthesis of new water soluble N-alkylated derivatives of 1,3,5-triaza-7-phosphaadamantane is presented. The compounds were characterized by means of NMR and IR spectroscopy, mass spectrometry, high resolution mass spectrometry, elemental analysis and X-ray diffraction analysis. The water solubility of these compounds was found to be up to an astonishing 1450 g/L. Several different reactions were performed utilizing these highly interesting compounds as starting materials. It was shown that the substitution of the counter ion can be performed easily. Also transformations at the PTA framework were possible, as shown by an ester cleavage example. To prove that the resulting PTA derivatives are competent as ligands for transition metals, gold(I) complexes were synthesized, using Au(tht)Cl as the metal source. The resulting gold(I) complexes were characterized by ~1H NMR and IR spectroscopy, mass and high resolution mass spectrometry or elemental analysis.
机译：介绍了新的1,3,5-三氮杂-7-磷金刚烷水溶性N-烷基化衍生物的合成。通过NMR和IR光谱，质谱，高分辨率质谱，元素分析和X射线衍射分析来表征化合物。发现这些化合物的水溶性高达惊人的1450 g / L。利用这些非常有趣的化合物作为起始原料，进行了几种不同的反应。结果表明，可以容易地进行抗衡离子的取代。如酯裂解实例所示，在PTA框架上的转化也是可能的。为了证明所得的PTA衍生物可作为过渡金属的配体，使用Au（tht）Cl作为金属源合成了金（I）配合物。生成的金（I）配合物通过〜1 H NMR和IR光谱，质谱和高分辨率质谱法或元素分析进行​​表征。

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