Bitriazole bridged manganese(II) framework with weak ferromagnet behavior

Jia L.-H.; Liu A.-C.; Wang B.-W.; Wang Z.-M.; Gao S.

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Bitriazole bridged manganese(II) framework with weak ferromagnet behavior

机译：铁磁体性能较弱的双三唑桥连锰（II）骨架

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An asymmetric bridging ligand 3,4′-bi-1,2,4-triazole (Hbtr) was used for constructing transition metal coordination polymer, and yielding a manganese(II) compound [Mn(btr) _2] _n (1) with a unique three-dimensional (3D) framework. Single-crystal X-ray diffraction reveals that 1 crystallizes in the orthorhombic space group Fdd2 and the structure is 3D (3, 6)-connected topological framework constructed from manganese ions and μ _3-btr ligands. The magnetic investigation for compound 1 shows that it is an antiferromagnetically coupled 3D array of high-spin manganese(II) ions with long-range ordering below T = 2.6 K, which is a weak ferromagnetic state due to spin-canting.

机译：使用不对称桥联配体3,4'-bi-1,2,4-三唑（Hbtr）来构建过渡金属配位聚合物，并得到锰（II）化合物[Mn（btr）_2] _n（1）独特的三维（3D）框架。 X射线单晶衍射表明，1在正交晶体空间群Fdd2中结晶，其结构是由锰离子和μ_3-btr配体构成的3D（3，6）连接的拓扑框架。化合物1的磁性研究表明，它是高自旋锰（II）离子的反铁磁耦合3D阵列，其长程顺序低于T = 2.6 K，由于自旋倾斜，其为弱铁磁态。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2011年第18期|共4页
作者
Jia L.-H.; Liu A.-C.; Wang B.-W.; Wang Z.-M.; Gao S.;
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正文语种 eng
中图分类无机化学;
关键词
3; 4′-Bi-1; 2; 4-triazole; Coordination polymer; Magnetic properties; Manganese; Spin canting;

机译：3;4'-Bi-1;2;4-三唑;配位聚合物;磁性;锰;旋涂;

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1. Bitriazole bridged manganese(II) framework with weak ferromagnet behavior [J] . Jia L.-H., Liu A.-C., Wang B.-W., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2011,第18期

机译：铁磁体性能较弱的双三唑桥连锰（II）骨架
2. Weak Ferromagnetism and Dynamic Magnetic Behavior of Two 2D Compounds with Hydroxy/Carboxylate-Bridged Co(II) Chains [J] . Xiao-Ning Cheng, Wei Xue, Wei-Xiong Zhang Chemistry of Materials: A Publication of the American Chemistry Society . 2008,第16期

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8. Weak-Ferromagnetism of Quasi Two-Dimensional Manganese Stearate. [R] . Pomerantz, M., Aviram, A. 1976

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Bitriazole bridged manganese(II) framework with weak ferromagnet behavior

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