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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Effective photocatalytic degradation of organic pollutant by ZnS nanocrystals synthesized via thermal decomposition of single-source precursor
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Effective photocatalytic degradation of organic pollutant by ZnS nanocrystals synthesized via thermal decomposition of single-source precursor

机译:单一来源前驱物热分解合成的ZnS纳米晶体对有机污染物的有效光催化降解

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摘要

2-Aminocyclopentene-1-dithiocarboxylate complex of zinc(II) has been synthesized and found to be an effective single-source precursor for the preparation of ZnS NCs (rod and sphere) by the use of ethylenediamine and hexadecylamine as structure directing solvents. Structural characterizations were carried out using XRD, TEM and BET measurements and the optical properties by UV-Vis and PL spectroscopic techniques. The prepared ZnS NCs show effective photocatalytic activity towards the degradation of Rose Bengal dye (RB) under light irradiation for their probable application in waste water treatment. The degradation mechanism of RB dye under light irradiation is established by terephthalic acid photoluminescence probing technique.
机译:合成了锌(II)的2-氨基环戊烯-1-二硫代羧酸酯络合物,发现它是使用乙二胺和十六烷基胺作为结构导向溶剂制备ZnS NCs(棒和球)的有效单源前体。使用XRD,TEM和BET测量以及UV-Vis和PL光谱技术对光学性能进行结构表征。制备的ZnS NCs在光照射下对玫瑰红染料(RB)的降解表现出有效的光催化活性,很可能应用于废水处理。通过对苯二甲酸光致发光探测技术建立了RB染料在光照射下的降解机理。

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