1-D, 2-D and 3-D coordination polymers assembled from polynuclear Co ~(II) units based on the isophthalate(-2) ligand

Kim E.Y.; Song Y.J.; Koo H.G.; Lee J.H.; Park H.M.; Kim C.; Kwon T.-H.; Huh S.; Kim S.-J.; Kim Y.

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1-D, 2-D and 3-D coordination polymers assembled from polynuclear Co ~(II) units based on the isophthalate(-2) ligand

机译：由多核Co〜（II）单元基于间苯二甲酸（-2）配体组装而成的1-D，2-D和3-D配位聚合物

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Three polymeric complexes containing polynuclear Co~(II) units, [Co_2(Cbtp)_2(ip)_2] (1), [N(CH_3) _4]_2[Co_3(ip)_4] (2), and [{Co _7(ip)_5(μ-OH)_4}(μ-bpp)_2] ·2(H_2O) (3), have been prepared by solvothermal synthesis. Isophthalic acid (H_2ip) has been used for the construction of polynuclear Co~(II) units, and three auxiliary ligands, namely Cbtp, quinazoline, and bpp, have also been employed to change nuclearity of Co ~(II) unit and the dimensionality of polymeric Co~(II) compounds: 1-D structure containing dinuclear Co~(II) units with Cbtp, 2-D structure containing trinuclear Co~(II) units without quinazoline, and 3-D structure containing heptanuclear Co~(II) units with bpp. The gas sorption study of 3 revealed a relative high uptake of CO_2 over N_2 because of small dimension of channels. The thermal stabilities and magnetic properties of these complexes were also examined.

机译：包含多核Co〜（II）单元，[Co_2（Cbtp）_2（ip）_2]（1），[N（CH_3）_4] _2 [Co_3（ip）_4]（2）和[{Co溶剂热合成法制备了_7（ip）_5（μ-OH）_4}（μ-bpp）_2]·2（H_2O）（3）。间苯二甲酸（H_2ip）已用于构建多核Co〜（II）单元，并且还使用了三个辅助配体Cbtp，喹唑啉和bpp来改变Co〜（II）单元的核度和尺寸聚合的Co〜（II）化合物的结构：包含Cbtp的双核Co〜（II）单元的1-D结构，不含喹唑啉的包含三核Co〜（II）单元的2-D结构和包含七核Co〜（II）的3-D结构）单位为bpp。对3的气体吸附研究表明，由于通道尺寸较小，CO_2吸收的N_2相对较高。还检查了这些配合物的热稳定性和磁性。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2010年第18期|共7页
作者
Kim E.Y.; Song Y.J.; Koo H.G.; Lee J.H.; Park H.M.; Kim C.; Kwon T.-H.; Huh S.; Kim S.-J.; Kim Y.;
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正文语种 eng
中图分类无机化学;
关键词
Co~(II) complexes; Coordination polymers; Gas sorption; Isophthalic acid; Polynuclear Co~(II) units;

机译：Co〜（II）配合物;配位聚合物;气体吸附;间苯二甲酸;多核Co〜（II）单元;

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1-D, 2-D and 3-D coordination polymers assembled from polynuclear Co ~(II) units based on the isophthalate(-2) ligand

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