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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >New organotin carboxylates derived from 6-chloro-3-pyridineacetic acid exhibiting discrete molecular, drum-like, linear polymeric and ladder structures constructed from dimeric tetraorganodistannoxane units
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New organotin carboxylates derived from 6-chloro-3-pyridineacetic acid exhibiting discrete molecular, drum-like, linear polymeric and ladder structures constructed from dimeric tetraorganodistannoxane units

机译:衍生自6-氯-3-吡啶乙酸的新型有机锡羧酸盐,具有由二聚四有机二锡氧烷单元构成的离散的分子,鼓状,线性聚合物和梯形结构

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摘要

Seven new organotin (IV) carboxylates have been synthesized by the reactions of 6-chloro-3-pyridineacetic acid with triorganotin chloride and diorganotin dichloride. All the complexes were characterized by elemental analysis, IR, 1H NMR, 13C NMR, ~(119)Sn NMR and X-ray crystallography. The structural analyses show that all the complexes present various structures, including monomer, drum, 1D polymers and ladders. It is worth noting that complex 1 is a novel 1D spring-like helical chain containing guest solvent molecules.
机译:通过6-氯-3-吡啶乙酸与氯化三有机锡和二氯化二有机锡的反应合成了七种新的有机锡(IV)羧酸盐。通过元素分析,IR,1 H NMR,13 C NMR,〜(119)Sn NMR和X射线晶体学对所有配合物进行表征。结构分析表明,所有配合物均具有各种结构,包括单体,鼓,一维聚合物和梯子。值得注意的是,配合物1是一种新型的一维弹簧状螺旋链,包含客体溶剂分子。

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