Gold complexes with mono- or di-chalcogenides of bis(diphenylphosphino)methanide ligands. X-ray crystal structure of [Au(C6F5)(2){(SPPh2)(2)C(AuAsPh3)(2)}]ClO4

Alvarez B.; Gimeno MC.; Jones PG.; Laguna A. Lopez-de-Luzuriaga JM.; Fernandez EJ.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Gold complexes with mono- or di-chalcogenides of bis(diphenylphosphino)methanide ligands. X-ray crystal structure of [Au(C6F5)(2){(SPPh2)(2)C(AuAsPh3)(2)}]ClO4

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Gold complexes with mono- or di-chalcogenides of bis(diphenylphosphino)methanide ligands. X-ray crystal structure of [Au(C6F5)(2){(SPPh2)(2)C(AuAsPh3)(2)}]ClO4

机译：金与双（二苯基膦基）甲烷配体的单硫属元素或二硫属元素化物。 [Au（C6F5）（2）{（SPPh2）（2）C（AuAsPh3）（2）}] ClO4的X射线晶体结构

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The reaction between the chalcogenide derivatives [Au(C6F5)(3)(PPh2CH2PPh2E)] (E = S, O) and [Au(acac)PPh3] or [Au(TfO)PPh3] leads to the dinuclear compounds [Au(C6F5)(3){PPh2CH(AuPPh3)PPh2E}] (E = S, O) or [Au(C6F5)(3){PPh2CH2PPh2(SAuPPh3)}], respectively. When the phosphine disulphide complex [Au(C6F5)(3)(SPPh2CH2PPh2S)] is employed, the reaction with [Au(acac)PPh3] promotes the double substitution of the methylenic protons. The reaction of [Au(acac)L] (L = PPh3, AsPh3) with the six-membered auracycle [Au(C6F5)(2){(SPPh2)(2)CH2}]ClO4 leads to the double substitution of both methylenic protons by [AuL](+) fragments, keeping the auracycle intact. The crystal structure of one such product, [Au(C6F5)(2){(SPPh2)(2)C(AuAsPh3)(2)}]ClO4 has been established by X-ray diffraction studies. Starting from the methanide derivative [Au(C6F5)(2)(SPPh2CHPPh2S)], the reaction with [Au(acac)PPh3] leads to the synthesis of the four-membered ring methanide [Au(C6F5)(2){SPPh2C(AuPPh3)PPh2S}]. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 21]

机译：硫族化物衍生物[Au（C6F5）（3）（PPh2CH2PPh2E）（E = S，O）与[Au（acac）PPh3]或[Au（TfO）PPh3]之间的反应生成双核化合物[Au（C6F5））（3）{PPh2CH（AuPPh3）PPh2E}]（E = S，O）或[Au（C6F5）（3）{PPh2CH2PPh2（SAuPPh3）}]。当使用二硫化膦配合物[Au（C6F5）（3）（SPPh2CH2PPh2S）]时，与[Au（acac）PPh3]的反应促进亚甲基质子的双取代。 [Au（acac）L]（L = PPh3，AsPh3）与六元金环[Au（C6F5）（2）{（SPPh2）（2）CH2}] ClO4的反应导致两个亚甲基的双取代质子由[AuL]（+）片段组成，保持金环完整无缺。通过X射线衍射研究已经确定了一种这样的产物[Au（C6F5）（2）{（SPPh2）（2）C（AuAsPh3）（2）}] ClO4的晶体结构。从甲烷化物衍生物[Au（C6F5）（2）（SPPh2CHPPh2S）]开始，与[Au（acac）PPh3]的反应导致四元环甲烷化物[Au（C6F5）（2）{SPPh2C（ AuPPh3）PPh2S}]。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：21]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第12期|共7页
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Alvarez B.; Gimeno MC.; Jones PG.; Laguna A. Lopez-de-Luzuriaga JM.; Fernandez EJ.;
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1. Gold complexes with mono- or di-chalcogenides of bis(diphenylphosphino)methanide ligands. X-ray crystal structure of [Au(C6F5)(2){(SPPh2)(2)C(AuAsPh3)(2)}]ClO4 [J] . Alvarez B., Gimeno MC., Jones PG., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第11a12期

机译：金与双（二苯基膦基）甲烷配体的单硫属元素或二硫属元素化物。 [Au（C6F5）（2）{（SPPh2）（2）C（AuAsPh3）（2）}] ClO4的X射线晶体结构
2. Silver and gold trinuclear complexes based on 3-substituted or 3,5-disubstituted pyrazolato ligands. X-ray crystal structure of cyclo-tris{mu-[3,5-bis(4-phenoxyphenyl)-1H-pyrazolato-kappa N-1 :kappa N-2]}trigold dichloromethane ([Au(mu-pz(pp2))](3) c [J] . Torralba MC., Ovejero P., Mayoral MJ., Helvetica chimica acta . 2004,第1期

机译：基于3取代或3,5-二取代吡唑并配体的银和金三核络合物。环tris {mu- [3,5-双（4-苯氧基苯基）-1H-吡唑并合κN-1：κN-2]}三金二氯甲烷（[Au（mu-pz（pp2 ））]（3）c
3. New gold(I) and silver(I) complexes with organophosphorus ligands with SPNSO skeleton. Crystal and molecular structures of monomeric [Au{(SPPh2)(O2SR)N}(PPh3)] (R = Me, C6H4Me-4) and dimeric [Ag{(SPPh2)(O2SPh)N}(PPh3)]22CH2Cl2 [J] . Alpar Pollnitz, Anca Silvestru, M. Concepcion Gimeno, Inorganica Chimica Acta . 2010,第2期

机译：新的金（I）和银（I）与具有SPNSO骨架的有机磷配体配合物。单体[Au {（SPPh2）（O2SR）N}（PPh3）]（R = Me，C6H4Me-4）和二聚体[Ag {（SPPh2）（O2SPh）N}（PPh3）] 22CH2Cl2的晶体和分子结构
4. Single Electron Tunneling in Molecular Nanostructures of Crystalline Gold Clusters Attached by Dithiols to Au 111: Direct I(V) Measurements of Individual Surface Attached Gold Clusters by STM [C] . Clifford P. Kubiak, Ronald P. Andres, Thomas Bein, NATO Advanced Research Workshop on Modular Chemistry . 1997

机译：通过二硫醇与Au附着的结晶金簇的分子纳米结构中的单电子隧道111：STM的单个表面附加金簇的直接I（v）测量
5. Substitution chemistry of the cobalt complexes R carbon cobalt(3) nonacarbonyl (R = hydrogen, formyl radical) with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Syntheses, x-ray structures, and reactivity. [D] . Liu, Jie. 2001

机译：用二膦配体4,5-双（二苯基膦基）-4-环戊烯-1,3-二酮（bpcd）取代钴络合物R的碳（9）碳羰基钴（R =氢，甲酰基）：合成，x射线结构和反应性。
6. Syntheses X-ray Crystal Structures and Solution Behavior of Monomeric Cationic Two-Coordinate Gold(I) π-Alkene Complexes [O] . Timothy J. Brown, Marina G. Dickens, Ross A. Widenhoefer -1

机译：合成X射线晶体结构和单体的溶液行为阳离子两坐标金（I）π烯烃配合
7. New gold(I) and silver(I) complexes with organophosphorus ligands with SPNSO skeleton. Crystal and molecular structures of monomeric Au{(SPPh2)(O2SR)N}(PPh3) (R = Me, C6H4Me-4) and dimeric Ag{(SPPh2)(O2SPh)N}(PPh3)2·2CH2Cl2 [O] . Pöllnitz Alpar, Silvestru Anca, Gimeno M. Concepción, 2012

机译：新的金（I）和银（I）与具有SPNSO骨架的有机磷配体配合。单体Au {（SPPh2）（O2SR）N}（PPh3）（R = Me，C6H4Me-4）和二聚体Ag {（SPPh2）（O2SPh）N}（PPh3） 2·2CH2Cl2的晶体和分子结构
8. Synthesis and X-ray Crystal Structures of (Au(CH2)2PPh2)2(CF3)2, (Au(CH2)2PPh2)2(C6F5)2, and (PPN)(Au(C6F5)4): Two Dinuclear Gold (II) Ylide Complexes Containing Alkyl and Aryl Ligands and a Tetrakis(pentafluorophenyl)aurate(III) [R] . Murray, H. H., Fackler, J. P., Porter, L. C., 1987

机译：（au（CH2）2pph2）2（CF3）2，（au（CH2）2pph2）2（C6F5）2和（ppN）（au（C6F5）4）的合成和X射线晶体结构：两个双核金（ II）含有烷基和芳基配体的Ylide配合物和四（五氟苯基）丙酸酯（III）

Gold complexes with mono- or di-chalcogenides of bis(diphenylphosphino)methanide ligands. X-ray crystal structure of [Au(C6F5)(2){(SPPh2)(2)C(AuAsPh3)(2)}]ClO4

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