Synthesis and structure of a two-dimensional copper(II) coordination polymer with 3,4,9,10-perylenetetracarboxylic acid and ethylenediamine

Suenaga Y.; Munakata M.; Maekawa M.; Kuroda-Sowa T.

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Synthesis and structure of a two-dimensional copper(II) coordination polymer with 3,4,9,10-perylenetetracarboxylic acid and ethylenediamine

机译：3,4,9,10-per四甲酸与乙二胺的二维铜（II）配位聚合物的合成与结构

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The crystal and molecular structure of a dinuclear copper(II) complex with 3,4,9,10-perylenetetracarboxylic acid (H(4)ptca) and ethylenediamine (en) [Cu-2(en)(4)(mu-ptca)] (EtOH)(2)(H2O)(6) has been determined by X-ray structural analysis. Each copper atom is coordinated by four-nitrogen atoms of two en molecules, one oxygen atom of bridging ptca(4-) and one water molecule in an octahedral arrangement. The resulting dinuclear copper(II) complex forms two-dimensional network through intermolecular hydrogen bonds between carboxylate of ptca4- and the water. (C) 1998 Elsevier Science Ltd; All rights reserved. [References: 13]

机译：具有3,4,9,10-per四甲酸（H（4）ptca）和乙二胺（en）[Cu-2（en）（4）（mu-ptca）的双核铜（II）配合物的晶体和分子结构）]（EtOH）（2）（H2O）（6）已通过X射线结构分析确定。每个铜原子由两个en分子的四个氮原子配位，一个氧原子桥接ptca（4-）和一个水分子呈八面体排列。所得的双核铜（II）配合物通过ptca4-的羧酸盐与水之间的分子间氢键形成二维网络。（C）1998 Elsevier Science Ltd;版权所有。 [参考：13]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第14期|共5页
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Suenaga Y.; Munakata M.; Maekawa M.; Kuroda-Sowa T.;
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中图分类化学;无机化学;
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1. Synthesis and structure of a two-dimensional copper(II) coordination polymer with 3,4,9,10-perylenetetracarboxylic acid and ethylenediamine [J] . Suenaga Y., Munakata M., Maekawa M., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第13a14期

机译：3,4,9,10-per四甲酸与乙二胺的二维铜（II）配位聚合物的合成与结构
2. Synthesis, crystal structure and magnetic properties of a two-dimensional cyanide-based heterometallic coordination polymer with cationic piperazinium ligands: poly[aquatetra-μ2-cyanido-κ8C:N-dicyanido-κ2C-(piperazinium-κN4)cobalt(III)copper(II)] [J] . Qin Ying-Lian, Yao Chen-Zhong, Yang Bin-Wu, Acta crystallographica. Section C, Structural chemistry. . 2016,第1期

机译：带有阳离子哌嗪鎓配体的基于氰化物的二维杂金属配位聚合物的合成，晶体结构和磁性II）]
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4. Synthesis, Structures and Properties of Two New Three-dimensional Ce(III) Coordination Polymers with 2,2'-bipyridine-4,4'-dicarboxylic Acid [C] . Ruiping Zheng, Huiyuan Chen, Junjie He, International Conference on Advanced Engineering Materials and Technology . 2013

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5. Studies on 3,4,9,10-perylenetetracarboxylic acid diimide based ligands as G-quadruplex DNA interactive agents. [D] . Kern, Jonathan Thurston. 2002

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7. Synthesis, Crystal Structure and Luminescent Property of a New Two-Dimensional Zn(II) Coordination Polymer Based on Oxalic Acid and 1,4-Bis(imidazol-1-ylmethyl)-benzene [O] . Qing-Wei Wang, Xiao-Fei Qi, Xiu-Mei Li, 2013

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8. Inorganic Coordination Polymers. Part XIX. Steric Effects of Hydrocarbon Side Groups on the Structure and Properties of Zinc(II),Cobalt(II),Manganese(II),Nickel(II) and Copper(II) Bis(Phosphinates). [R] . gillman, h. d. eichelberger, j. l. 1975

机译：无机配位聚合物。第十九部分。烃侧基的立体效应对锌（II），钴（II），锰（II），镍（II）和铜（II）双（次膦酸盐）的结构和性质的影响。

Synthesis and structure of a two-dimensional copper(II) coordination polymer with 3,4,9,10-perylenetetracarboxylic acid and ethylenediamine

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