Synthesis and characterization of monomeric and dimeric palladium(II)-ammonium complexes: their use for the catalytic oxidation of alcohols

Sandrine Bouquillon; Amaury du Moulinet dHardemare; Marie-Therese Averbuch-Pouchot; Francoise Henin; Jacques Muzart

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Synthesis and characterization of monomeric and dimeric palladium(II)-ammonium complexes: their use for the catalytic oxidation of alcohols

机译：单体和二聚钯（II）-铵络合物的合成与表征：它们用于醇的催化氧化

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The addition of quaternary ammonium salts, R_4NX, to PdCl_2 leads to mononuclear anionic complexes: (R_4N)_2PdX_4. A dinuclear complex, (n-Bu_4N)_2Pd_2Cl_6, has been characterized from the crystallization of the corresponding monomeric species under controlled conditions. These complexes revealed a similar efficiency as mixtures of PdCl_2 and R_4NX for the catalytic oxidation of alcohols using 1,2-dichloroethane as both solvent and stoichiometric oxidant.

机译：向PdCl_2中添加季铵盐R_4NX会生成单核阴离子络合物：（R_4N）_2PdX_4。通过在控制条件下相应单体的结晶，可以表征出一种双核络合物（n-Bu_4N）_2Pd_2Cl_6。这些络合物显示出与PdCl_2和R_4NX的混合物相似的效率，该混合物使用1,2-二氯乙烷作为溶剂和化学计量氧化剂来催化氧化醇。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1999年第26期|共6页
作者
Sandrine Bouquillon; Amaury du Moulinet dHardemare; Marie-Therese Averbuch-Pouchot; Francoise Henin; Jacques Muzart;
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正文语种 eng
中图分类化学;无机化学;
关键词
catalysis; oxidation; complexes; palladium; quaternary ammonium salts; X-ray structure;

机译：催化;氧化;络合物;钯;季铵盐;X射线结构;

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1. Synthesis and characterization of monomeric and dimeric palladium(II)-ammonium complexes: their use for the catalytic oxidation of alcohols [J] . Sandrine Bouquillon, Amaury du Moulinet dHardemare, Marie-Therese Averbuch-Pouchot, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1999,第26期

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机译：还原三元钼氧化物和可溶性铜（III）醇盐配合物的合成和表征。

Synthesis and characterization of monomeric and dimeric palladium(II)-ammonium complexes: their use for the catalytic oxidation of alcohols

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