THE FIRST MO2FE2S2 CLUSTER COMPOUND WITH FUNCTIONALLY SUBSTITUTED CYCLOPENTADIENYL LIGAND - SYNTHESIS AND CRYSTAL STRUCTURE OF (ETA(5)-MEO(2)CC(5)H(4))(2)(MU-3CO)(2)MO2FE2(MU(3)-S)(2)(CO)(6)

Song LC.; Hu QM.; Wang JQ.

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THE FIRST MO2FE2S2 CLUSTER COMPOUND WITH FUNCTIONALLY SUBSTITUTED CYCLOPENTADIENYL LIGAND - SYNTHESIS AND CRYSTAL STRUCTURE OF (ETA(5)-MEO(2)CC(5)H(4))(2)(MU-3CO)(2)MO2FE2(MU(3)-S)(2)(CO)(6)

机译：具有功能性取代环戊二烯基配体的第一个MO2FE2S2簇化合物-（ETA（5）-MEO（2）CC（5）H（4））（2）（MU-3CO）（2）MO2FE2（MU（FE））的合成和晶体结构3）-S）（2）（CO）（6）

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Reaction of (eta(5)-MeO(2)CC(5)H(4))(2)Mo-2(CO)(4) with (mu-S-2) Fe-2(CO)(6) in CH2Cl2 at room temperature gave the cluster compound (eta(5)-MeO(2)CC(5)H(4))(2)(mu(3)-CO)(2)Mo2Fe2(mu(3)-S)(2)(CO6), the structure of which was confirmed by X-ray diffraction analysis. [References: 8]

机译：（eta（5）-MeO（2）CC（5）H（4））（2）Mo-2（CO）（4）与（mu-S-2）Fe-2（CO）（6）的反应在室温下于CH2Cl2中制得簇化合物（eta（5）-MeO（2）CC（5）H（4））（2）（mu（3）-CO）（2）Mo2Fe2（mu（3）-S ）（2）（CO6），其结构通过X射线衍射分析确认。 [参考：8]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1995年第8期|共3页
作者
Song LC.; Hu QM.; Wang JQ.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Metal multiple bonds; Complexes;

机译：金属多重键;络合物;

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1. THE FIRST MO2FE2S2 CLUSTER COMPOUND WITH FUNCTIONALLY SUBSTITUTED CYCLOPENTADIENYL LIGAND - SYNTHESIS AND CRYSTAL STRUCTURE OF (ETA(5)-MEO(2)CC(5)H(4))(2)(MU-3CO)(2)MO2FE2(MU(3)-S)(2)(CO)(6) [J] . Song LC., Hu QM., Wang JQ. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1995,第8期

机译：具有功能性取代环戊二烯基配体的第一个MO2FE2S2簇化合物-（ETA（5）-MEO（2）CC（5）H（4））（2）（MU-3CO）（2）MO2FE2（MU（FE））的合成和晶体结构3）-S）（2）（CO）（6）
2. Preparation and characterization of Mo_2C_2, Co_2Mo_2C_2 clusters containing functionally substituted cyclopentadienyl ligands. The crystal structures of [Mo_2(#mu#-C_2HPh)(CO)_4(#eta#~5-C_5H_4C(O)Me)_2] and [Co_2Mo_2(#mu#_4-C_2HPh)(#mu#-CO)_4(CO)_4 [J] . Jie Zhang, Xue-Nian Chen, Yuan-Qi Yin, Journal of Organometallic Chemistry . 1999,第1a2期

机译：含有功能取代的环戊二烯基配体的Mo_2C_2，Co_2Mo_2C_2簇的制备与表征。 [Mo_2（＃mu＃-C_2HPh）（CO）_4（＃eta＃〜5-C_5H_4C（O）Me）_2]和[Co_2Mo_2（＃mu＃_4-C_2HPh）（＃mu＃-CO）的晶体结构_4（CO）_4
3. SYNTHESIS, CHARACTERIZATION, AND REACTIONS OF THE CLUSTER COMPLEXES CONTAINING THE TETRAHEDRAL CLUSTER CORE MFECOS (M=MO, W) AND A FUNCTIONALLY SUBSTITUTED CYCLOPENTADIENYL LIGAND - THE SINGLE CRYSTAL X-RAY STRUCTURES OF TWO DOUBLE CLUSTERS, [ETA(5)- [J] . Song LC., Hu QM., Huang XY., Organometallics . 1995,第1期

机译：包含四面体簇核MFECOS（M = MO，W）和功能取代的环戊二烯配体-两个（两个）双（五个）的单晶体X射线结构的簇复合物的合成，表征和反应
4. Synthesis and Structures of Novel Early-Late Heterometallic Polyhydrido Complexes with Cyclopentadienyl Ligands [C] . Yasumasa Takenaka, Jens Baldamus, Zhaomin Hou Symposium on Organometallic Chemistry . 2004

机译：基于环戊二烯基配体的新型早期杂核聚络合物的合成与结构
5. Kinetics and mechanisms of the ligand substitution reactions of cyclopentadienyl M tetracarbonyl, indenyl M tetracarbonyl, M = niobium or tantalum, and molybdenum(2) (carbon monoxide)(6) [mu-eta(5),eta(5)-cyclopentadienylide-carbon alkyl(2)-cyclopentadienylide] with tributylphosphine, triphenylphosphine and triphenylphosphite. Photo-assisted carbonylation of supercritical ethane, ethane and methane in supercritical carbon dioxide by trans-chlorocarbonylbis(trimethylphosphine)rhodium(I). [D] . Lukmanova-Kline, Dinara Maratovna. 2001

机译：动力学和机制的环戊二烯基M四羰基，茚基M四羰基，M =铌或钽和钼（2）（一氧化碳）（6）[mu-eta（5），eta（5）-cyclopentadienylide-碳烷基（2）-环戊二烯基]与三丁基膦，三苯基膦和亚磷酸三苯酯。通过反氯羰基双（三甲基膦）铑（I）在超临界二氧化碳中对超临界乙烷，乙烷和甲烷进行光辅助羰基化。
6. Cubane-type Fe4S4 Clusters with Chiral Thiolate Ligation: Formation by Ligand Substitution Detection of Intermediates by 1H NMR and Solid State Structures Including Spontaneous Resolution Upon Crystallization [O] . Wayne Lo, Shaw Huang, Shao-Liang Zheng, -1

机译：立方烷型Fe4s4集群手性硫醇盐结扎：形成由配体取代中间体的检测通过1H NmR和固态结构包括自发性分辨率结晶时
7. Synthesis of new bis(cyclopentadienyl)yttrium complexes with ether functionalized cyclopentadienyl ligands. Crystal structure of (C5H4CH2CH2OMe)2Y(μ-H)2BH2 [O] . Laske Dietmar A., Duchateau Robbert, Teuben Jan H., 1993

机译：具有醚官能化的环戊二烯基配体的新双（环戊二烯基）钇配合物的合成。 C5H4CH2CH2OMe）2Y（μ-H）2BH2的晶体结构
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 93. Synthesis of Heteropolynuclear Metal Compounds with Chains of Seven to Eleven Metal Atoms; Crystal Structure of (Mo2W3Pt6(Mu3-CMe)3(Mu3-CC6H4Me-4)2(CO)10(PMe2Ph)4(Eta-C5H5)5). [R] . Davies, S. J., Howard, J. A., Musgrove, R. J., 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。第93部分。具有7至11个金属原子链的杂多核金属化合物的合成; （mo2W3pt6（mu3-Cme）3（mu3-CC6H4me-4）2（CO）10（pme2ph）4（Eta-C5H5）5）的晶体结构。

THE FIRST MO2FE2S2 CLUSTER COMPOUND WITH FUNCTIONALLY SUBSTITUTED CYCLOPENTADIENYL LIGAND - SYNTHESIS AND CRYSTAL STRUCTURE OF (ETA(5)-MEO(2)CC(5)H(4))(2)(MU-3CO)(2)MO2FE2(MU(3)-S)(2)(CO)(6)

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