Synthesis, crystal structure and reactivity of the dihydroborate [Li(Et2O)][B(C6F5)(2)(H)(2)]

Douthwaite RE.

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Synthesis, crystal structure and reactivity of the dihydroborate [Li(Et2O)][B(C6F5)(2)(H)(2)]

机译：二氢硼酸盐[Li（Et2O）] [B（C6F5）（2）（H）（2）]的合成，晶体结构和反应活性

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The new dihydroborate [Li(Et2O)][B(C6F5)(2)(H)(2)] (1) has been prepared and characterised by single-crystal X-ray diffraction. In the solid state 1 exhibits a one-dimensional chain structure that is a result of intermolecular Li-F interactions. Reaction between 1 and one equivalent of Cp2TiCl or 0.5 equivalents of Cp2TiCl2 gives the violet compound Cp2Ti{(mu-H)(2)B(C6F5)(2)} (2), which has also been characterised by single-crystal X-ray diffraction. Addition of two equivalents of PM3, to 2 does not result in elimination of a borane:phosphine adduct, but yields the ionic compound [Cp2Ti(PMe3)(2)][H2B(C6F5)(2)] (3). (C) 2000 Elsevier Science Ltd. All rights reserved. [References: 16]

机译：制备了新的二氢硼酸盐[Li（Et2O）] [B（C6F5）（2）（H）（2）]（1），并通过单晶X射线衍射进行了表征。在固态1中显示出一维链结构，这是分子间Li-F相互作用的结果。 1与1当量的Cp2TiCl或0.5当量的Cp2TiCl2之间的反应产生了紫罗兰色化合物Cp2Ti {（mu-H）（2）B（C6F5）（2）}（2），其特征还在于单晶X-射线衍射。将两当量的PM3加到2不会消除硼烷：膦加合物，但会产生离子化合物[Cp2Ti（PMe3）（2）] [H2B（C6F5）（2）]（3）。（C）2000 Elsevier ScienceLtd。保留所有权利。 [参考：16]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2000年第13期|共5页
作者
Douthwaite RE.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Hydroborates; Lithium; Titanium(iv); Bonding; Crystal structures; Transition-metal; Complexes;

机译：氢硼酸盐;锂;钛（iv）;键合;晶体结构;过渡金属;配合物;

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1. Synthesis, crystal structure and reactivity of the dihydroborate [Li(Et2O)][B(C6F5)(2)(H)(2)] [J] . Douthwaite RE. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第13期

机译：二氢硼酸盐[Li（Et2O）] [B（C6F5）（2）（H）（2）]的合成，晶体结构和反应活性
2. SYNTHESIS, STRUCTURE AND REACTIVITY OF STABLE DIANIONIC ORGANOMETALLIC COMPLEXES OF PT(IV) - CRYSTAL STRUCTURE OF [PETPH(3)](2)[CIS-PT(C6F5)(2)CL-4] AND [NBU(4)][MER-PT(C6F5)(2)CL-3(NH2-P-C6H4CH3)] [J] . Casas JM., Oliva J., Tomas M., Inorganica Chimica Acta . 1995,第1a2期

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3. Synthesis and reactivity of N-heterocycle-B(C6F5)(3) complexes. 4. Competition between pyridine- and pyrrole-type substrates toward B(C6F5)(3): Structure and dynamics of 7-B(C6F5)(3)-7-azaindole and [7-azaindolium](+)[HOB(C6F5)(3)](-) [J] . Focante F, Camurati I, Resconi L, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第4期

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8. Synthesis and X-ray Crystal Structures of (Au(CH2)2PPh2)2(CF3)2, (Au(CH2)2PPh2)2(C6F5)2, and (PPN)(Au(C6F5)4): Two Dinuclear Gold (II) Ylide Complexes Containing Alkyl and Aryl Ligands and a Tetrakis(pentafluorophenyl)aurate(III) [R] . Murray, H. H., Fackler, J. P., Porter, L. C., 1987

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Synthesis, crystal structure and reactivity of the dihydroborate [Li(Et2O)][B(C6F5)(2)(H)(2)]

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