Copper(II) and nickel(II) complexes of 5-methyl-2-hydroxyacetophenone N(4)-substituted thiosemicarbazones

Labisbal E.; Haslow KD.; Sousa-Pedrares A.; Valdes-Martinez J. Hernandez-Ortega S.; West DX.

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Copper(II) and nickel(II) complexes of 5-methyl-2-hydroxyacetophenone N(4)-substituted thiosemicarbazones

机译：5-甲基-2-羟基苯乙酮N（4）取代的硫代半咔唑的铜（II）和镍（II）配合物

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Mononuclear and binuclear copper(II) and nickel(II) complexes with 5-methyl-2-hydroxyacetophenone N(4)-substituted thiosemicarbazones have been prepared and characterized. IR and H-1 NMR spectra of the N(4)-substituted thiosemicarbazones and their metal complexes, as well as ESR spectra of the mononuclear copper(II) complexes, have been obtained. The crystal structures of 5-methyl-2-hydroxyacetophenone N(4)-dimethylthiosemicarbazone and a representative binuclear copper(II) complex have been acquired, and their structural features are compared to related thiosemicarbazones and previously reported binuclear copper(II) thiosemicarbazone complexes. (C) 2003 Elsevier Ltd. All rights reserved. [References: 36]

机译：制备并表征了具有5-甲基-2-羟基苯乙酮N（4）-取代的硫代半氨基甲酮的单核和双核铜（II）和镍（II）配合物。已获得N（4）-取代的硫代半脲酮及其金属配合物的IR和H-1 NMR光谱，以及单核铜（II）配合物的ESR光谱。已经获得了5-甲基-2-羟基苯乙酮N（4）-二甲基硫半碳酮和代表性的双核铜（II）配合物的晶体结构，并将它们的结构特征与相关的硫代半碳氮酮和先前报道的双核铜（II）硫代半碳烯配合物进行了比较。（C）2003 Elsevier Ltd.保留所有权利。 [参考：36]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2003年第20期|共7页
作者
Labisbal E.; Haslow KD.; Sousa-Pedrares A.; Valdes-Martinez J. Hernandez-Ortega S.; West DX.;
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正文语种 eng
中图分类化学;
关键词
Hydroxyacetophenone; Thiosemicarbazone; Copper; Nickel; Crystal structures; Metal(ii) complexes; 2-hydroxyacetophenone n-4-substituted thiosemicarbazones; Crystal-structure; Palladium(ii) complexes; Cobalt(iii) complexes; Tripalladium complex; Metal-complexes; Ligands; N(4)-dimethylthiosemicarbazone; N(4)-methylthiosemicarbazone; Esr;

机译：羟基苯乙酮;硫代氨基脲;铜;镍;晶体结构;金属（ii）配合物;2-羟基苯乙酮n-4-取代的硫代氨基甲酮;晶体结构;钯（ii）配合物;钴（iii）配合物;三钯配合物;金属配合物;配体;N（4）-二甲基硫代氨基脲;N（4）-甲基硫代氨基脲;Esr;

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1. Copper(II) and nickel(II) complexes of 5-methyl-2-hydroxyacetophenone N(4)-substituted thiosemicarbazones [J] . Labisbal E., Haslow KD., Sousa-Pedrares A., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2003,第20期

机译：5-甲基-2-羟基苯乙酮N（4）取代的硫代半咔唑的铜（II）和镍（II）配合物
2. Halo-substituted thiosemicarbazones and their copper(II), nickel(II) complexes: Detailed spectroscopic characterization and study of antitumour activity against HepG2 human hepatoblastoma cells [J] . M. Jagadeesh, Suresh K. Kalangi, L. Sivarama Krishna, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2014,第Null期

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3. 2,6-Diacetyl-and 2,6-diformylpyridine bis(N4-substituted thiosemicarbazones) and their copper(II) and nickel(II) complexes [J] . Christine A.Brown, Douglas X.West Transition Metal Chemistry . 2003,第2期

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4. Highly polarizable metallic complexes for nonlinear optics copper(II) andnickel(II) complexes of bis(salicylaldiminato) Schiff base, [C] . Abdalla M. Darwish, Alabama AM Univ., Huntsville, Nonlinear Optical Properties of Organic Materials IX . 1996

机译：高极化金属配合物，用于双（水杨基铝亚胺）Schiff碱的非线性光学铜（II）和镍（II）配合物，
5. Chemistry of copper peptide complexes: Alkoxide coordination in copper(II) and copper(III) peptide complexes, and base decomposition of copper(III) peptide complexes [D] . Wang, Lihua. 1991

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8. Studies of the Complexes Formed Between the 5-Trifluoromethyletetrazol Anion and Some Divalent Transition Metal Ions. Magnetochemical and Spectral Studies of Some Copper (II) Complexes of Substituted Benzoic Acids. Copper (II) Halide Complexes with Substituted Pyridine n-Oxides [R] . Harris, A. D., Jonassen, H. B., Mallory, T. L., 1964

机译：5-三氟甲基四唑阴离子与一些二价过渡金属离子形成的配合物的研究。一些取代苯甲酸铜（Ⅱ）配合物的磁化学和光谱研究。具有取代的吡啶n-氧化物的铜（II）卤化物配合物

Copper(II) and nickel(II) complexes of 5-methyl-2-hydroxyacetophenone N(4)-substituted thiosemicarbazones

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