INDIUM(III) COMPLEXES WITH TRIDENTATE NITROGEN DONOR LIGANDS - SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF COMPLEXES WITH PYRIDINE-2,6-BIS(ACETYLOXIME) AND 2,6-BIS(1-PHENYLIMINOETHYL)PYRIDINE

Abram S.; Abram U.; Maichlemossmer C.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >INDIUM(III) COMPLEXES WITH TRIDENTATE NITROGEN DONOR LIGANDS - SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF COMPLEXES WITH PYRIDINE-2,6-BIS(ACETYLOXIME) AND 2,6-BIS(1-PHENYLIMINOETHYL)PYRIDINE

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INDIUM(III) COMPLEXES WITH TRIDENTATE NITROGEN DONOR LIGANDS - SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF COMPLEXES WITH PYRIDINE-2,6-BIS(ACETYLOXIME) AND 2,6-BIS(1-PHENYLIMINOETHYL)PYRIDINE

机译：三价氮供体配体的铟（III）配合物-吡啶-2,6-双（乙氧基）和2,6-双（1-苯亚甲基亚乙基）吡啶的配合物的合成，表征和晶体结构

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2,6-Bis (acetyloxime)pyridine, 2,6-C5H3N(C2H3NOH)(2) (L-1), reacts with indium(III) chloride in methanol to give the seven-coordinate complex [InCl3(L-1)(MeOH)]. The structurally similar Schiff base ligand 2,6-bis(1-phenyliminoethyl)pyridine (L-2), 2,6-C5H3N(C2H3NC6H5)(2), however, forms a six-coordinate indium(III) complex of the composition [InCl3(L-2)]. The In-N bond distances are longer by 0.03-0.12 Angstrom in the seven-coordinate compound compared with those in the Schiff base complex. The MeOH ligand in [InCl3(L-1)(MeOH)] can be replaced by Cl- or H2O to give the complex anion [InCl4(L-1)](-) and [InCl3(L-1)(OH2)], respectively. The pentagonal-bipyramidal coordination environment of the metal is preserved during these reactions. (C) 1997 Elsevier Science Ltd. [References: 11]

机译：2,6-双（乙酰肟）吡啶2,6-C5H3N（C2H3NOH）（2）（L-1）在甲醇中与氯化铟（III）反应生成七配位化合物[InCl3（L-1）（MeOH）]。结构相似的席夫碱配体2,6-双（1-苯基亚氨基乙基）吡啶（L-2），2,6-C5H3N（C2H3NC6H5）（2）形成了六配位的铟（III）配合物[InCl 3（L-2）]。与席夫碱配合物相比，七配位化合物的In-N键距离长0.03-0.12埃。 [InCl3（L-1）（MeOH）]中的MeOH配体可被Cl-或H2O取代，得到配位阴离子[InCl4（L-1）]（-）和[InCl3（L-1）（OH2） ]，分别。在这些反应过程中保留了金属的五角-双锥体配位环境。（C）1997 Elsevier Science Ltd. [参考：11]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第13期|共9页
作者
Abram S.; Abram U.; Maichlemossmer C.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Indium complexes; Oximes; Nitrogen donor ligands; Crystal structure;

机译：铟配合物氧氮供体配体晶体结构;

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1. INDIUM(III) COMPLEXES WITH TRIDENTATE NITROGEN DONOR LIGANDS - SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF COMPLEXES WITH PYRIDINE-2,6-BIS(ACETYLOXIME) AND 2,6-BIS(1-PHENYLIMINOETHYL)PYRIDINE [J] . Abram S., Abram U., Maichlemossmer C. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第13期

机译：三价氮供体配体的铟（III）配合物-吡啶-2,6-双（乙氧基）和2,6-双（1-苯亚甲基亚乙基）吡啶的配合物的合成，表征和晶体结构
2. Nickel and copper complexes based on tridentate nitrogen donor ligand 2,6-bis-(1-phenyliminoethyl) pyridine: Synthesis, spectral and structural characterization [J] . Trivedi M, Pandey DS, Xu Q Inorganica Chimica Acta . 2007,第7期

机译：基于三齿氮供体配体2,6-双-（1-苯基亚氨基乙基）吡啶的镍和铜配合物：合成，光谱和结构表征
3. Iron(II)- and cobalt(II) complexes with tridentate bis(imino)pyridine nitrogen ligands bearing chiral bulky aliphatic and aromatic substituents: Crystal structure of [CoCl2{2,6-bis[R-(+)-(bornylimino)methyl]pyridine}] [J] . Lappalainen K, Yliheikkila K, Abu-Surrah AS, Zeitschrift fur Anorganische und Allgemeine Chemie . 2005,第4期

机译：具有手性庞大脂肪族和芳香族取代基的三齿双（亚氨基）吡啶氮配体的铁（II）和钴（II）配合物：[CoCl2 {2,6-双[R-（+）-（降冰片基）]甲基]的晶体结构] pyridine}]
4. Substituent Effect in Spin-Crossover Behavior of Iron(II)-Ar-pybox Complexes (Ar-pybox= 4-Aryl-2,6-bis(oxazolin-2-yl)pyridine) [C] . Akifumi Kimura, Takayuki Ishida Irago Conference . 2018

机译：铁（II）-AR-ubox络合物的旋转交叉行为中的取代基效应（Ar-pybox = 4-芳基-2,6-双（恶唑啉-2-基）吡啶）
5. Tridentate nitrogen ligands derived from 2,6-bis-hydrazinopyridine (BHP): Preparation and study of the 2,6-bis-hydrazonopyridines, 2,6-bis-pyrazolylpyridines, and 2,6-bis-indazolylpyridines. [D] . Duncan, Nathan C. 2009

机译：源自2,6-双-肼基吡啶（BHP）的三齿氮配体：2,6-双-肼基吡啶，2,6-双-吡唑基吡啶和2,6-双-吲唑基吡啶的制备和研究。
6. Studies on Some New Ru(III) Complexes Using aryl-azo Pentane-2,4-dione and 2,6-bis (2'-Benzimidazolyl) Pyridine as Ligands:Synthesis, Spectroscopic, Luminescent, Electrochemical and Biological Activities [O] . Lallan Mishra, Ajay K. Yadaw, Ratna S. Phadke, 1947

机译：用芳基偶氮戊烷-研究一些新的Ru（III）配合物2,4-二酮和2,6-双（2'-苯并咪唑基）吡啶为配体：合成，光谱，发光，电化学和生物活性
7. Synthesis, Structures, and Olefin Polymerization Characteristics of Group 4 Catalysts Zr{(OAr)2py}Cl2(D) (D = O-Donors, ClHPR3) Supported by Tridentate Pyridine-2, 6-bis(aryloxide) Ligands [O] . -1

机译：第4族催化剂的合成，结构和烯烃聚合特性Zr {（OAR）2 PY} Cl2（d）（D = O-供体，Cl HPR3）由三乙嘧啶-2,6-双（芳氧化物）负载配体

INDIUM(III) COMPLEXES WITH TRIDENTATE NITROGEN DONOR LIGANDS - SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF COMPLEXES WITH PYRIDINE-2,6-BIS(ACETYLOXIME) AND 2,6-BIS(1-PHENYLIMINOETHYL)PYRIDINE

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