Radical cation salts of TTF(CH2OH)(4) with cyanide anions: Synthesis, crystal structure and magnetic properties of [TTF(CH2OH)(4)][TCNQF(4)] and [TTF(CH2OH)(4)](3)[18-crown-6 subset of K][M(CN)(6)]center dot DMF (M = Fe, Co)

Perruchas S; Boubekeur K; Molinie P

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Radical cation salts of TTF(CH2OH)(4) with cyanide anions: Synthesis, crystal structure and magnetic properties of [TTF(CH2OH)(4)][TCNQF(4)] and [TTF(CH2OH)(4)](3)[18-crown-6 subset of K][M(CN)(6)]center dot DMF (M = Fe, Co)

【24h】

Radical cation salts of TTF(CH2OH)(4) with cyanide anions: Synthesis, crystal structure and magnetic properties of [TTF(CH2OH)(4)][TCNQF(4)] and [TTF(CH2OH)(4)](3)[18-crown-6 subset of K][M(CN)(6)]center dot DMF (M = Fe, Co)

机译：TTF（CH2OH）（4）与氰化物阴离子的自由基阳离子盐：[TTF（CH2OH）（4）] [TCNQF（4）]和[TTF（CH2OH）（4）]（3的合成，晶体结构和磁性）[K的[18-crown-6子集] [M（CN）（6）]中心点DMF（M = Fe，Co）

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The electrocrystallization synthesis, X-ray crystal structures and magnetic properties of three radical cation salts, [TTF(CH2OH)(4)][TCNQF(4)] (1) and [TTF(CH2OH)(4)](3)[18-crown-6 subset of K][M(CN)(6)] - DMF with M = Fe (2a) and M = Co (2b), are described. These salts associate the hydroxyl-functionalized organic donor tetrakis(hydroxymethyl)tetrathiafulvalene (TTF(CH2OH)4) with two different types of cyanide anions. In the structures, the organic molecules are combined in electronically isolated and diamagnetic dimers (1) or trimers (2a-b). The structural analysis reveals strong hydrogen bonds between the hydroxyl groups of the organic molecules and also between the latter and the cyano groups of the anions. This study shows that the association of hydrogen bond acceptor anions to hydrogen bond donor functionalized TTFs is a good strategy to produce new molecular materials with original structural organization. (c) 2005 Elsevier Ltd. All rights reserved.

机译：[TTF（CH2OH）（4）] [TCNQF（4）]（1）和[TTF（CH2OH）（4）]（3）[3]的电结晶合成，X射线晶体结构和磁性描述了K] [M（CN）（6）]-DMF的18冠-6子集，其中M = Fe（2a）和M = Co（2b）。这些盐使羟基官能化的有机供体四（羟甲基）四硫富瓦烯（TTF（CH2OH）4）与两种不同类型的氰化物阴离子缔合。在结构中，有机分子结合在电子隔离的和抗磁性的二聚体（1）或三聚体（2a-b）中。结构分析揭示了有机分子的羟基之间以及有机分子和阴离子的氰基之间的强氢键。这项研究表明，氢键受体阴离子与氢键供体官能化的TTF的缔合是生产具有原始结构组织的新分子材料的良好策略。（c）2005 Elsevier Ltd.保留所有权利。

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2005年第12期|共10页
作者
Perruchas S; Boubekeur K; Molinie P;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
radical cation salts; tetrathiafulvalene; hexacyanometalates; crystal structures; hydrogen bonds; electrocrystallization; CHARGE-TRANSFER SALTS; PI-ELECTRON DONORS; BEDT-TTF COLUMN; MOLECULAR MATERIALS; HYDROGEN-BOND; SOLID-STATE; PHASE-TRANSITIONS; METAL-COMPLEXES; CR-III; DIMENSIONALITY;

机译：自由基阳离子盐;四硫富瓦烯;六氰基金属酸盐;晶体结构;氢键;电结晶;电荷转移盐;PI电子供体;BEDT-TTF柱;分子物质;氢键;固相;相变;金属络合物;CR-III;尺寸;

相似文献

外文文献
中文文献

1. Radical cation salts of TTF(CH2OH)(4) with cyanide anions: Synthesis, crystal structure and magnetic properties of [TTF(CH2OH)(4)][TCNQF(4)] and [TTF(CH2OH)(4)](3)[18-crown-6 subset of K][M(CN)(6)]center dot DMF (M = Fe, Co) [J] . Perruchas S, Boubekeur K, Molinie P Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2005,第12期

机译：TTF（CH2OH）（4）与氰化物阴离子的自由基阳离子盐：[TTF（CH2OH）（4）] [TCNQF（4）]和[TTF（CH2OH）（4）]（3的合成，晶体结构和磁性）[K的[18-crown-6子集] [M（CN）（6）]中心点DMF（M = Fe，Co）
2. Crystal and electronic structure of (BEDT-TTF)2 Br CH2(OH)CH2OH and (EDT-TTF)3(HsqXH2sq) (H2sq = squaric acid) [J] . A. Miyazaki, K. Yamaguchi Synthetic Metals . 1999,第1a3期

机译：（BEDT-TTF）2 Br CH2（OH）CH2OH和（EDT-TTF）3（HsqXH2sq）（H2sq =方酸）的晶体和电子结构
3. Crystal and electronic structures of the radical cation salt based on EDT-TTF and the photochromic nitroprusside anion, (EDT-TTF)_3[Fe(CN)_5NO] [J] . L.V. Zorina, M. Gener, S.S. Khasanov Synthetic Metals . 2002,第3期

机译：基于EDT-TTF和光致变色亚硝基阴离子（EDT-TTF）_3 [Fe（CN）_5NO]的自由基阳离子盐的晶体和电子结构
4. Magnetic properties of the ClTET-TTF and the TMET-TTF based organic radical ion saltswith iron(Ⅲ) anions [C] . M. Enomoto China-Japan joint symposium on conduction and photoconduction in organic solids and related phenomena;CJOSS-7 . 2001

机译：ClTET-TTF和基于TMET-TTF的铁（Ⅲ）阴离子有机自由基离子盐的磁性
5. SYNTHESES, STRUCTURES, AND PROPERTIES OF NEW MULTI-CHALCOGEN TTF DERIVATIVES, THEIR CHARGE-TRANSFER COMPLEXES AND ION-RADICAL SALTS [D] . 中野, 英之 1991

机译：新型多卤代TTF衍生物，其电荷转移复合物和离子根盐的合成，结构和性质
6. Transition Metal Complexes and Radical Anion Salts of 110-Phenanthroline Derivatives Annulated with a 125-Tiadiazole and 125-Tiadiazole 11-Dioxide Moiety: Multidimensional Crystal Structures and Various Magnetic Properties [O] . Yoshiaki Shuku, Kunio Awaga 2014

机译：与125-噻二唑和125-噻二唑11-二氧化物部分环合的110-菲咯啉衍生物的过渡金属配合物和自由基阴离子盐：多维晶体结构和各种磁性
7. Hydrogen Bonds in Radical Cation Salts of TTF(CH2OH)4: First Complete Series with the Octahedral Rhenium Cluster Anions Re6S8-nCl6+nn-4 (n = 0, 1, 2, 3) [O] . -1

机译：TTF（CH 2 OH）4的自由基阳离子盐中的氢键（CH 2 OH）4：首先完整系列与八面体铼簇阴离子RE6S8-NCL6 + N N-4（n = 0,1,2,3）
8. Structure-property relationships for (beta)- and (kappa)-phase BEDT-TTF salts and their use in the synthesis of (kappa)-(BEDT-TTF)(sub 2)Cu(N(CN)(sub 2))Br. A salt having the highest-T(sub c) (inductive onset = 11.6K, resistive onset = 12.5K) yet observed [R] . Williams, J. M., Kini, A. M., Geiser, U., 1990

机译：（β）和（κ）相BEDT-TTF盐的结构 - 性质关系及其在（κ） - （BEDT-TTF）（sub 2）Cu（N（CN）（sub 2））合成中的用途BR。观察到具有最高-T（亚c）（诱导发作= 11.6K，电阻发作= 12.5K）的盐

Radical cation salts of TTF(CH2OH)(4) with cyanide anions: Synthesis, crystal structure and magnetic properties of [TTF(CH2OH)(4)][TCNQF(4)] and [TTF(CH2OH)(4)](3)[18-crown-6 subset of K][M(CN)(6)]center dot DMF (M = Fe, Co)

摘要

著录项

相似文献

相关主题

期刊订阅