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首页> 外文期刊>Chemical Reviews >Fullerenes in liquid media: An unsettling intrusion into the solution chemistry
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Fullerenes in liquid media: An unsettling intrusion into the solution chemistry

机译：液体介质中的富勒烯：对溶液化学的令人不安的入侵

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摘要

Researchers have made efforts to unify the results in terms of solution chemistry and colloid science of compounds including fullerenes (C _(60)). The most principal thermodynamic property of any compound with respect to solution chemistry is its solubility. A vast collection of solubility values in individual and mixed solvents for fullerenes, specifically C _(60) and C_(70) has been gathered. The solubility of fullerene molecules in the polar solvents is negligible despite their extremely high polarizability. The enhanced solubility in some nitrogen-containing liquids indicates the possibility of specific solvation or chemical modification of the fullerene molecule, making it worthwhile to regard such solvents as 'reactive' ones. The molar volume of the solid fullerene C_(60) is also independent of temperature and as a rule exceeds its partial molar volume in solution.
机译：研究人员已努力在溶液化学和包括富勒烯的化合物的胶体科学方面统一结果（C _（60））。就溶液化学而言，任何化合物最主要的热力学性质是其溶解度。已经收集了富勒烯在单独和混合溶剂中的大量溶解度值，特别是C_（60）和C_（70）。富勒烯分子在极性溶剂中的溶解度可以忽略不计，尽管它们具有极高的极化率。在某些含氮液体中溶解度的提高表明富勒烯分子可能发生特定的溶剂化或化学修饰，因此值得将这类溶剂视为“反应性”溶剂。固体富勒烯C_（60）的摩尔体积也与温度无关，通常超过其在溶液中的部分摩尔体积。

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