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Converting Carbon Dioxide into Carbamato Derivatives

机译:将二氧化碳转化为氨基甲酸酯衍生物

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This review article covers compounds containing the monoanionic N,N-dialkylcarbamato ligand,of formula O_2CNR_2~(-),R being H,an alkyl-,or an aryl group.Due to their relatively recent appearance in the literature,the metal-containing compounds of this class are believed to be covered exhaustively by this review.On the other hand,the R_2NH/CO_2 system,which is the basis for the subsequent development of this chemistry,has attracted the earlier interest of researchers since the beginning of last century,especially in connection with industrially relevant processes.Therefore,section 2 will be dedicated to a discussion of the available scientific information on the interaction of carbon dioxide with ammonia,and with primary and secondary amines.
机译:这篇综述文章涵盖了含有式O_2CNR_2〜(-)的单阴离子N,N-二烷基氨基甲酸酯配体的化合物,R为H,烷基或芳基。由于它们在文献中的出现相对较新,因此含有金属相信该综述已详尽涵盖了此类化合物。另一方面,自上世纪初以来,作为该化学后续发展的基础的R_2NH / CO_2系统引起了研究人员的较早兴趣。因此,第2节将专门讨论有关二氧化碳与氨,伯胺和仲胺相互作用的现有科学信息。

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