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Selective IR multiphoton dissociation of molecules in a pulsed gas-dynamically cooled molecular flow interacting with a solid surface as an alternative to low-energy methods of molecular laser isotope separation

机译:脉冲气动力冷却分子流中与固体表面相互作用的分子的选择性红外多光子解离,作为低能方法进行分子激光同位素分离的替代方法

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摘要

We report the results of studies on the isotope-selective infrared multiphoton dissociation (IR MFD) of SF6 and CF3I molecules in a pulsed, gas-dynamically cooled molecular flow interacting with a solid surface. The productivity of this method in the conditions of a specific experiment (by the example of SF6 molecules) is evaluated. A number of low-energy methods of molecular laser isotope separation based on the use of infrared lasers for selective excitation of molecules are analysed and their productivity is estimated. The methods are compared with those of selective dissociation of molecules in the flow interacting with a surface. The advantages of this method compared to the low-energy methods of molecular laser isotope separation and the IR MPD method in the unperturbed jets and flows are shown. It is concluded that this method could be a promising alternative to the low-energy methods of molecular laser isotope separation.
机译:我们报告了在与固体表面相互作用的脉冲,气体动力冷却分子流中SF6和CF3I分子的同位素选择性红外多光子解离(IR MFD)的研究结果。评估该方法在特定实验条件下的生产率(以SF6分子为例)。分析了许多基于红外激光对分子进行选择性激发的低能分子激光同位素分离方法,并估算了它们的生产率。将这些方法与在与表面相互作用的流中选择性解离分子的方法进行了比较。显示了与低能分子激光同位素分离方法和IR MPD方法相比,该方法在无扰动的射流和流动中的优势。结论是,该方法可以替代分子激光同位素分离的低能方法。

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