Trialkylammoniododecaborates: Anions for ionic liquids with potassium, lithium and protons as cations

Justus E; Rischka M; Wishart JF; Werner K; Gabel D

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Trialkylammoniododecaborates: Anions for ionic liquids with potassium, lithium and protons as cations

机译：三烷基氨基十二烷脱硼酸盐：离子液体的阴离子，钾，锂和质子为阳离子

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Herein we report a new class of low-melting ionic liquids (IL) that consist of N,N,N-trialkylammonioundecahydrododecaborates(1-) as the anion and a range of cations. The cations include the common cations of conventional ILs such as tetraalkylammonium, N-alkylpyridinium, and N-methyl-N ''-alkylimidazolium. In addition, their salts with lithium, potassium, and proton cations also exist as ILs. Pulse radiolysis studies indicate that the anions do not react with solvated electrons.

机译：在这里，我们报告了一类新型的低熔点离子液体（IL），该离子液体由N，N，N-三烷基氨磺酰二十氢十二硼酸酯（1-）作为阴离子和一系列阳离子组成。阳离子包括常规IL的常见阳离子，例如四烷基铵，N-烷基吡啶鎓和N-甲基-N'-烷基咪唑鎓。另外，它们与锂，钾和质子阳离子的盐也以IL形式存在。脉冲辐射分解研究表明，阴离子不会与溶剂化电子发生反应。

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《Chemistry: A European journal》 |2008年第6期|共6页
作者
Justus E; Rischka M; Wishart JF; Werner K; Gabel D;
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正文语种 eng
中图分类化学;
关键词
boranes; boron; conducting materials; ionic liquids; lithium; pulse radiolysis; WEAKLY COORDINATING ANIONS; ROOM-TEMPERATURE; CARBORANE ANIONS; SALTS; SOLVENTS; DERIVATIVES; CATALYSIS; CHEMISTRY; B10H10-2; BORANES;

机译：硼烷;硼;导电材料;离子液体;锂;脉冲辐解;弱配位阴离子;室温;碳硼烷阴离子;盐;溶剂;衍生物;催化;化学性质;B10H10-2;硼烷;

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专利

1. Trialkylammoniododecaborates: Anions for ionic liquids with potassium, lithium and protons as cations [J] . Justus E, Rischka M, Wishart JF, Chemistry: A European journal . 2008,第6期

机译：三烷基氨基十二烷脱硼酸盐：离子液体的阴离子，钾，锂和质子为阳离子
2. Toxicity of N,N,N-trialkylammoniododecaborates as new anions of ionic liquids in cellular, liposomal and enzymatic test systems [J] . Tanja Schaffran, Eugen Justus, Maike Elfert Green chemistry . 2009,第9期

机译：N，N，N-三烷基氨基碘代十二烷的毒性降低，可作为细胞，脂质体和酶促测试系统中离子液体的新阴离子
3. Influence of Polar Organic Solvents in an Ionic Liquid Containing Lithium Bis(fluorosulfonyl)amide: Effect on the Cation-Anion Interaction, Lithium Ion Battery Performance, and Solid Electrolyte Interphase [J] . Lahiri Abhishek, Li Guozhu, Olschewski Mark, ACS applied materials & interfaces . 2016,第49期

机译：含双（氟磺酰基）酰胺锂的离子液体中极性有机溶剂的影响：对阳离子-阴离子相互作用，锂离子电池性能和固体电解质界面的影响
4. Electrochemical Properties of Ionic Liquids Containing Aprotic Heterocyclic Anions (AHA ILs) and Their Mixtures with Lithium Salts [C] . Liyuan Sun, Han Xia, Oscar Morales-Collazo, PRiME Joint International Meeting of the Electrochemical Society, the Electrochemical Society of Japan, and the Korean Electrochemical Society . 2016

机译：非质子杂环（AHA ILS）的离子液体的电化学性质及其与锂盐的混合物
5. Hemeproteins bathed in ionic liquids: Examining the role of water and protons in redox behavior and catalytic function [D] . Moran, John J. 2009

机译：浸入离子液体中的血红蛋白：检查水和质子在氧化还原行为和催化功能中的作用
6. Investigating the Proton and Ion Transfer Properties of Supported Ionic Liquid Membranes Prepared for Bioelectrochemical Applications Using Hydrophobic Imidazolium-Type Ionic Liquids [O] . László Koók, Piroska Lajtai-Szabó, Péter Bakonyi, 2021

机译：使用疏水性咪唑型离子液体对生物电化学应用制备的负载离子液体膜的质子和离子转移性能
7. Effect of cation structure on the oxygen solubility and diffusivity in a range of bis{(trifluoromethyl)sulfonyl}imide anion based ionic liquids for lithium-air battery electrolytes [O] . Neale, Alex, Li, Peilin, Jacquemin, Johan, 2016

机译：阳离子结构对一系列用于锂空气电池电解质的双{（（三氟甲基）磺酰基}酰亚胺阴离子液体中的氧溶解度和扩散系数的影响
8. Thermodynamic, Dynamic, and Structural Properties of Ionic Liquids Comprised of 1-butyl-3-methylimidazolium Cation and Nitrate, Azide, or Dicyanamide Anions [R] . Bedrov, D., Borodin, O. 2010

机译：离子液体的热力学，动力学和结构性质，由1-丁基-3-甲基咪唑阳离子和硝酸盐，叠氮化物或二氰胺阴离子组成

Trialkylammoniododecaborates: Anions for ionic liquids with potassium, lithium and protons as cations

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