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The Role of Building-Block Metrics in the Halogen-Bonding-Driven Self-Assembly of Calixarenes, Inorganic Salts and Diiodoperfluoroalkanes

机译:砌块度量标准在杯形芳烃,无机盐和二碘全氟烷烃的卤素键驱动自组装中的作用。

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摘要

Halogen bonding effectively co-operates with ion–ion interactions in determining the supramolecular structure of three-component heteromeric crystals comprising of calix[4]arenes, inorganic salts and diiodoperfluoroalkanes. The subtle interplay between these two types of interactions, as well as the influence of the valence of the metal ion, the “size” of the calixarene platform and the length of the perfluorocarbon module on the stoichiometry and overall supramolecular organisation of the ternary supramolecular architectures is discussed. The relevance to the overall packing of the size matching between the pitches along the cationic and anionic sub-lattices is also discussed.
机译:在确定由杯[4]芳烃,无机盐和二碘全氟烷烃组成的三组分异聚晶体的超分子结构时,卤素键有效地与离子-离子相互作用配合使用。这两种相互作用之间的微妙相互作用,以及金属离子的化合价,杯芳烃平台的“大小”和全氟化碳模块的长度对三元超分子结构的化学计量和整体超分子组织的影响讨论。还讨论了沿阳离子和阴离子亚晶格的间距之间的尺寸匹配与总体填充的相关性。

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