Highly Enantioselective One-Pot, Three-Component Mannich-type Reaction Catalyzed by an N,N '-Dioxide-Scandium(III) Complex

Chen SK; Hou ZR; Zhu Y; Wang J; Lin LL; Liu XH; Feng XM

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Highly Enantioselective One-Pot, Three-Component Mannich-type Reaction Catalyzed by an N,N '-Dioxide-Scandium(III) Complex

机译：N，N'-二氧化物-Scan（III）配合物催化的高对映选择性一锅，三组分曼尼希型反应

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摘要

Optically active b-amino esters are important precursors for the preparation of natural products, pharmaceutical agents, and mimics of protein structural motifs.

机译：旋光性b-氨基酯是制备天然产物，药物制剂和蛋白质结构基序模拟物的重要前体。

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《Chemistry: A European journal》 |2009年第24期|共4页
作者
Chen SK; Hou ZR; Zhu Y; Wang J; Lin LL; Liu XH; Feng XM;
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正文语种 eng
中图分类应用化学;
关键词
One-Pot; Three-Component; Mannich-type;

机译：一锅三成分曼尼希型;

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专利

1. Highly Enantioselective One-Pot, Three-Component Mannich-type Reaction Catalyzed by an N,N '-Dioxide-Scandium(III) Complex [J] . Chen SK, Hou ZR, Zhu Y, Chemistry: A European journal . 2009,第24期

机译：N，N'-二氧化物-Scan（III）配合物催化的高对映选择性一锅，三组分曼尼希型反应
2. Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water [J] . Xiao J, Loh TP Synlett . 2007,第5期

机译：耐水手性铟配合物的设计与合成：在水中一锅三组分曼尼希型反应中的应用
3. One-Pot Three-Component Mannich-Type Reaction Catalyzed by Trifluoromethanesulfonic Acid in Water [J] . Li G, Wu HK, Wang ZY, Kinetics and catalysis . 2011,第1期

机译：三氟甲磺酸在水中催化一锅三组分曼尼希型反应
4. Highly Enantioselective Diels-Alder Reactions of Danishefsky's-type Dienes with Electron-Deficient Alkenes Catalyzed by Yb(III)-BINAMIDE Complexes [C] . Daisuke Shirasaki, Yukinori Sudo, Shinji Harada Symposium on Organometallic Chemistry . 2007

机译：Danishefsky的二烯酰胺酰胺反应达到易用的Yb（III） - 苯胺配合物催化的电子缺乏烯烃
5. Catalytic enantioselective synthesis of O-and N-substituted quaternary carbon stereogenic centers: 1. Aluminum-catalyzed alkylations of alpha-ketoesters with dialkylzinc reagents. 2. Silver-catalyzed vinylogous Mannich-type reactions of alpha-ketoimine esters with siloxyfurans [D] . Wieland, Laura Caroline 2008

机译：O和N取代的季碳立构中心的催化对映选择性合成：1.用二烷基锌试剂进行铝催化的α-酮酸酯的烷基化。 2.α-酮亚胺酯与甲硅烷氧基呋喃的银催化乙烯基曼尼希型反应
6. Highly Enantioselective Three-Component Direct Mannich Reactions of Unfunctionalized Ketones Catalyzed by Bifunctional Organocatalysts [O] . Qunsheng Guo, John Cong-Gui Zhao -1

机译：非官能化酮催化的高对映三组分直接曼尼希反应的双功能有机催化剂
7. Three-component carbon-carbon bond-forming reactions for the synthesis of β-amino carbonyl compounds using maleic acid-catalyzed one-pot mannich-type reaction in ethanol [O] . Malek Taher-Maghsoodlou, Seyyed Rasul-Mousavi, Ali Roygar, 2018

机译：三分组分碳 - 碳键合成形反应，用于在乙醇中使用马来酸催化的单罐曼尼希型反应合成β-氨基羰基化合物

Highly Enantioselective One-Pot, Three-Component Mannich-type Reaction Catalyzed by an N,N '-Dioxide-Scandium(III) Complex

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