ScIII-Doped Zeolites as New Heterogeneous Catalysts: Mukaiyama Aldol Reaction

Andrea Olmos; Aurlien Alix; Jean Sommer; Patrick Pale

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ScIII-Doped Zeolites as New Heterogeneous Catalysts: Mukaiyama Aldol Reaction

机译：ScIII掺杂的沸石作为新型多相催化剂：Mukaiyama Aldol反应

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ScIII-doped solids based on zeolite materials have been investigated for the first time as catalysts in organic synthesis. ScIII–USY zeolite proved to be a novel and very efficient heterogeneous catalyst for the Mukaiyama aldol reaction. This easy-to-prepare catalyst exhibited wide scope and compatibility with functional groups and is very simple to use, easy to remove (by simple filtration), and is recyclable (up to three times without loss of activity).

机译：首次研究了基于沸石材料的Sc3掺杂固体作为有机合成催化剂。 ScIII–USY沸石被证明是Mukaiyama羟醛反应的一种新型且非常有效的非均相催化剂。这种易于制备的催化剂显示出广泛的范围和与官能团的相容性，并且非常易于使用，易于除去（通过简单过滤）并且可循环使用（最多可回收三次，而不会损失活性）。

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《Chemistry: A European journal》 |2009年第42期|共6页
作者
Andrea Olmos; Aurlien Alix; Jean Sommer; Patrick Pale;
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正文语种 eng
中图分类应用化学;
关键词
aldol reaction; heterogeneous catalysis; scandium; zeolites;

机译：羟醛反应;多相催化;scan;沸石;

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专利

1. ScIII-Doped Zeolites as New Heterogeneous Catalysts: Mukaiyama Aldol Reaction [J] . Andrea Olmos, Aurlien Alix, Jean Sommer, Chemistry: A European journal . 2009,第42期

机译：ScIII掺杂的沸石作为新型多相催化剂：Mukaiyama Aldol反应
2. Synthesis and application of tin triflate-containing MCM-41 as heterogeneous Lewis acid catalysts for the Mukaiyama aldol reaction at room temperature [J] . Masakazu Saito, Hikaru Ikeda, Yu Horiuchi, Research on Chemical Intermediates . 2014,第1期

机译：含三氟甲磺酸锡的MCM-41作为非均相路易斯酸催化剂在室温下进行Mukaiyama羟醛反应的合成与应用
3. Silica sulfuric acid as a reusable heterogeneous catalyst for the diastereoselective Mukaiyama aldol reaction of 2-(trimethylsilyloxy)furan: facile synthesis of γ-butenolides [J] . Gowravaram Sabitha, M. Nagendra Prasad, M. Ramesh, Monatshefte für Chemie / Chemical Monthly . 2010,第11期

机译：二氧化硅硫酸作为2-（三甲基甲硅烷氧基）呋喃的非对映选择性Mukaiyama醛醇缩合反应的可重复使用的多相催化剂：γ-丁烯内酯的简便合成
4. Mechanism of MOF-505 and Cu-ZSM-5 Promoted Mukaiyama Aldol Reaction: An ONIOM study [C] . Sudarat Yadnum, Saowapak Choomwattana, Pipat Khongpracha, Nanotechnology 2009 : Technical proceedings . 2009

机译：MOF-505和Cu-ZSM-5促进Mukaiyama Aldol反应的机理：ONIOM研究
5. Total Synthesis of Lagunamide A via Remote Vinylogous Mukaiyama Aldol Reactions, Chemical Studies Toward the Total Synthesis of Micromide and Preliminary Studies Toward the Total Synthesis of Azaspirene. [D] . Banasik, Brent Andrew. 2016

机译：通过遥远的葡萄酒性Mukaiyama Aldol反应进行Lagunamide A的总合成，对杀微生物剂的总合成进行化学研究，对氮杂螺碳烯的总合成进行初步研究。
6. Chiral Zn(II)-Bisamidine Complex as a Lewis-Brønsted Combined Acid Catalyst: Application to Asymmetric Mukaiyama Aldol Reactions of α-Ketoesters [O] . Ryo Gotoh, Masahiro Yamanaka 2012

机译：Lewis-Brønsted组合酸催化剂的手性Zn（II）-二is胺配合物：在α-酮酸酯的不对称Mukaiyama Aldol反应中的应用
7. -Organic Lewis Acid Catalysis- Vinylogous Mukaiyama Aldol Reactions And New Catalysts [O] . Ratjen Lars 2012

机译：-有机路易斯酸催化-乙烯基类Mukaiyama Aldol反应和新催化剂

ScIII-Doped Zeolites as New Heterogeneous Catalysts: Mukaiyama Aldol Reaction

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