High-spin cyclopentadienyl complexes: A single-molecule magnet based on the aryl-iron(II) cyclopentadienyl type

Weismann D.; Sun Y.; Lan Y.; Wolmersh?user G.; Powell A.K.; Sitzmann H.

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High-spin cyclopentadienyl complexes: A single-molecule magnet based on the aryl-iron(II) cyclopentadienyl type

机译：高自旋环戊二烯基络合物：基于芳基-铁（II）环戊二烯基类型的单分子磁体

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The mononuclear high-spin iron(II) complex 1, coordinated by a pentaisopropylcyclopentadienide and an aryl group (see graphic), has been prepared and characterized by X-ray diffraction analysis. AC magnetic studies have revealed that this species exhibits slow magnetic relaxation and has the characteristics of a single-molecule magnet.

机译：已制备了由五异丙基环戊二烯和一个芳基配位的单核高自旋铁（II）配合物1（见图），并通过X射线衍射分析对其进行了表征。交流磁研究表明，该物质表现出缓慢的磁弛豫并具有单分子磁体的特性。

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《Chemistry: A European journal》 |2011年第17期|共5页
作者
Weismann D.; Sun Y.; Lan Y.; Wolmersh?user G.; Powell A.K.; Sitzmann H.;
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正文语种 eng
中图分类应用化学;
关键词
cyclopentadienyl ligands; high-spin complexes; iron; magnetic properties; single-molecule magnets; tunneling;

机译：环戊二烯基配体;高自旋络合物;铁;磁性;单分子磁体;隧道效应;

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1. High-spin cyclopentadienyl complexes: A single-molecule magnet based on the aryl-iron(II) cyclopentadienyl type [J] . Weismann D., Sun Y., Lan Y., Chemistry: A European journal . 2011,第17期

机译：高自旋环戊二烯基络合物：基于芳基-铁（II）环戊二烯基类型的单分子磁体
2. High-Spin Cyclopentadienyl Complexes: A Single-Molecule Magnet Based on the Aryl-Iron(II) Cyclopentadienyl Type? [J] . Daniel Weismann, Dr. Yu Sun, Dr. Yanhua Lan, Chemistry - A European Journal . 2011,第17期

机译：高自旋环戊二烯基络合物：基于芳铁（II）环戊二烯基类型的单分子磁体？
3. Cover Picture: High-Spin Cyclopentadienyl Complexes: A Single-Molecule Magnet Based on the Aryl-Iron(II) Cyclopentadienyl Type (Chem. Eur. J. 17/2011) [J] . Daniel Weismann, Dr. Yu Sun, Dr. Yanhua Lan, Chemistry - A European Journal . 2011,第17期

机译：封面图片：高自旋环戊二烯基络合物：基于芳基铁（II）环戊二烯基类型的单分子磁体（Chem。Eur。J. 17/2011）
4. Effect of Cyclopentadienyl Fragment in Polymerization of Ethylene, Propylene, and Styrene by Nonbridged Half-Metalloce Type Titanium and Zirconium Complexes of the Type, Cp'MCI_2 N(2,6-Me_2 C_6 H_3)(SiMe_3), -MAO Catalyst Systems [C] . Kotohiro NOMURA, Kensaku FUJII Tokyo Conference on Advanced Catalytic Science and Technology . 2003

机译：乙烯，丙烯和苯乙烯聚合对乙烯，苯乙烯的聚合的影响，CP'MCI_2 n（2,6-ME_2C_6 H_3），-MAO催化剂体系
5. The chemistry of alkyne adduct complexes of the cyclopentadienyl-based cobalt cluster dicobalt tris(cyclopentadienyl cobalt) [D] . King, William David 1996

机译：环戊二烯基钴簇二钴三（环戊二烯基钴）的炔烃加合物的化学性质
6. Synthesis and Reactivity of Cyclopentadienyl Ruthenium(II)Complexes with Tris(alkylthio)benzenes: Transformation between Dinuclearand Sandwich-Type Complexes [O] . Rong Fan, Ryo Sumitani, Tomoyuki Mochida 2020

机译：环戊二烯基钌（II）的合成与反应活性与三（烷硫基）苯的配合物：双核之间的转化和三明治型复合物
7. Syntheses and Reactivity of Group 6 Metallocene-type Complexes Based on Bis(.ETA.-cyclopentadienyl)molybdenum and -tungsten Fragments [O] . Takashi Ito, Yoshitaka Yamaguchi 2004

机译：基于双（乙烯基化苯基）钼和-Tungsten碎片的6族茂金属 - 型配合物的合成及反应性
8. Preparation of Cyclopentadienyl Cobalt(III),and eta-Cyclopentadienyl Nickel(IV) Complexes of the (eta-7-B10CH11)(3-) Carbollide Ligand. [R] . rietz,richard r. dustin,donald f. 1974

机译：制备环戊二烯基钴（III）和（η-7-B10CH11）（3-）Carbollide配体的η-环戊二烯基镍（IV）配合物。

High-spin cyclopentadienyl complexes: A single-molecule magnet based on the aryl-iron(II) cyclopentadienyl type

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