On the NH effect in ruthenium-catalysed hydrogenation of ketones: Rational design of phosphine-amino-alcohol ligands for asymmetric hydrogenation of ketones

Phillips S.D.; Fuentes J.A.; Clarke M.L.

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On the NH effect in ruthenium-catalysed hydrogenation of ketones: Rational design of phosphine-amino-alcohol ligands for asymmetric hydrogenation of ketones

机译：关于钌催化的酮氢化中的NH效应：酮不对称氢化的膦-氨基-醇配体的合理设计

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Chemical equation presented Redesign and reduce: The graphic shows some Ru complexes of tridentate ligands that do not contain NH substituents but can catalyse ketone reduction with zero-order dependence on ketone. In tridentate systems, a secondary amine, not a primary amine, promotes hydrogen activation. Leading on from these observations, the Ru complex of a phosphine-amino-alcohol shown above has been found to be a good hydrogenation catalyst.

机译：重新设计并还原了化学方程式：该图显示了一些三齿配体的Ru配合物，这些配合物不含NH取代基，但可以催化酮的还原，对酮的零级依赖性。在三齿体系中，仲胺而不是伯胺会促进氢活化。从这些观察结果出发，发现上述所示的膦-氨基醇的Ru络合物是良好的氢化催化剂。

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《Chemistry: A European journal》 |2010年第27期|共4页
作者
Phillips S.D.; Fuentes J.A.; Clarke M.L.;
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正文语种 eng
中图分类应用化学;
关键词
Chirality; Hydrogenation; Kinetics; Phosphines; Tridentate ligands;

机译：手性加氢动力学膦Tr状配体;

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1. On the NH effect in ruthenium-catalysed hydrogenation of ketones: Rational design of phosphine-amino-alcohol ligands for asymmetric hydrogenation of ketones [J] . Phillips S.D., Fuentes J.A., Clarke M.L. Chemistry: A European journal . 2010,第27期

机译：关于钌催化的酮氢化中的NH效应：酮不对称氢化的膦-氨基-醇配体的合理设计
2. P-Stereogenic PN(H)P Iron(II) Catalysts for the Asymmetric Hydrogenation of Ketones: The Importance of Non-Covalent Interactions in Rational Ligand Design by Computation [J] . Huber Raffael, Passera Alessandro, Gubler Erik, Advanced synthesis & catalysis . 2018,第15期

机译：用于酮的不对称氢化的P-立体型PN（H）催化剂：计算下的非共价相互作用的重要性
3. P-Stereogenic PN(H)P Iron(II) Catalysts for the Asymmetric Hydrogenation of Ketones: The Importance of Non-Covalent Interactions in Rational Ligand Design by Computation [J] . Huber Raffael, Passera Alessandro, Gubler Erik, Advanced synthesis & catalysis . 2018,第15期

机译：用于酮的不对称氢化的P-立体型PN（H）催化剂：计算下的非共价相互作用的重要性
4. Effective Asymmetric Transfer Hydrogenation of Ketones Catalyzed by A New Chiral P-N-P Ligand-Ruthenium Complexes [C] . Yoji Oderaotoshi, Yuki Noguchi, Satoshi Minakata Symposium on Organometallic Chemistry . 2006

机译：新的手性P-N-P配体 - 钌配合物催化的酮催化的有效不对称转移氢化
5. Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of aromatic ketones using new ferrocene-based amino-phosphine ligands featuring planar chirality [D] . Vue, Bao 2008

机译：使用具有平面手性的新型二茂铁基氨基膦配体，钌（II）催化芳族酮的不对称转移氢化
6. New phosphine-diamine and phosphine-amino-alcohol tridentate ligands for ruthenium catalysed enantioselective hydrogenation of ketones and a concise lactone synthesis enabled by asymmetric reduction of cyano-ketones [O] . José A Fuentes, Scott D Phillips, Matthew L Clarke 2012

机译：用于钌催化酮的对映选择性氢化的新膦二胺和膦氨基氨基醇三齿配体以及通过不对称还原氰基酮实现的简洁内酯合成
7. New phosphine-diamine and phosphine-amino-alcohol tridentate ligands for ruthenium catalysed enantioselective hydrogenation of ketones and a concise lactone synthesis enabled by asymmetric reduction of cyano-ketones [O] . José A Fuentes, Scott D Phillips, Matthew L Clarke 2013

机译：用于钌催化酮的对映选择性氢化的新膦二胺和膦氨基氨基醇三齿配体，以及通过不对称还原氰基酮实现的简洁内酯合成

On the NH effect in ruthenium-catalysed hydrogenation of ketones: Rational design of phosphine-amino-alcohol ligands for asymmetric hydrogenation of ketones

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