Catalytic asymmetric domino Michael-Henry reaction: Enantioselective access to bicycles with consecutive quaternary ceuters by using bifunctional catalysts

Rueping M.; Kuenkel A.; Fr?hlich R.

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Catalytic asymmetric domino Michael-Henry reaction: Enantioselective access to bicycles with consecutive quaternary ceuters by using bifunctional catalysts

机译：催化不对称多米诺骨牌迈克尔-亨利反应：使用双功能催化剂对具有连续季铵盐的自行车进行对映选择性访问

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"Chemical Equotion Presentation" Domino catalysis: Two consecutive quaternary stereocenters, three functional groups, and four stereogenic centers have been created in the newly developed domino Michael-Henry reaction (see scheme) employing small amounts of a bifunctional organocatalyst.

机译：“化学引物表示法” Domino催化：在新开发的多米诺骨牌Michael-Henry反应（参见方案）中，使用少量的双功能有机催化剂，已经创建了两个连续的季铵立体中心，三个官能团和四个立体中心。

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《Chemistry: A European journal》 |2010年第14期|共4页
作者
Rueping M.; Kuenkel A.; Fr?hlich R.;
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正文语种 eng
中图分类应用化学;
关键词
Cascade reactions; Domino reactions; Hydrogen bonds; Organocatalysis; Thioureas;

机译：级联反应;多米诺反应;氢键;有机催化;硫脲;

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1. Catalytic asymmetric domino Michael-Henry reaction: Enantioselective access to bicycles with consecutive quaternary ceuters by using bifunctional catalysts [J] . Rueping M., Kuenkel A., Fr?hlich R. Chemistry: A European journal . 2010,第14期

机译：催化不对称多米诺骨牌迈克尔-亨利反应：使用双功能催化剂对具有连续季铵盐的自行车进行对映选择性访问
2. Catalytic Asymmetric Domino Michael–Henry Reaction: Enantioselective Access to Bicycles with Consecutive Quaternary Centers by Using Bifunctional Catalysts [J] . Magnus Rueping Prof. Dr., Alexander Kuenkel Dipl.-Chem., Roland Frouml, Chemistry - A European Journal . 2010,第14期

机译：催化不对称多米诺·迈克尔·亨利反应：使用双功能催化剂对具有连续四元中心的自行车进行对映选择性访问
3. Bifunctional Squaramide Catalysts with the Same Absolute Chirality for the Diastereodivergent Access to Densely Functionalised Cyclohexanes through Enantioselective Domino Reactions. Synthesis and Mechanistic Studies [J] . Martinez Jose I., Villar Laura, Uria Uxue, Advanced synthesis & catalysis . 2014,第17期

机译：具有相同绝对手性的双功能方酰胺催化剂，通过对映选择性多米诺反应非对映异构地获得稠密官能化的环己烷。综合与机理研究
4. Homogeneous and heterogeneous asymmetric reactions. Part 13. Claysupported noble metal catalysts in enantioselective hydrogenations [C] . Bela Torok, Katalin Balazsik, Istvan Kun, International FEZA conference on porous materials in environmentally friendly processes . 1999

机译：均匀和异质的不对称反应。第13部分粘结性氢化的粘屑贵金属催化剂
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Asymmetric Synthesis of Spirocyclopentane OxindolesContaining Four Consecutive Stereocenters and Quaternary α-NitroEsters via Organocatalytic Enantioselective Michael–MichaelCascade Reactions [O] . PrakashD. Chaudhari, Bor-Cherng Hong, *, 2019

机译：螺环戊烷氧化吲哚的不对称合成包含四个连续的立体中心和第四级α-硝基通过有机催化对映选择性迈克尔-迈克尔酯级联反应
7. New Entries in Lewis Acid-Lewis Base Bifunctional Asymmetric Catalyst: Catalytic Enantioselective Reissert Reaction of Pyridine Derivatives [O] . -1

机译：路易斯酸-lewis碱基双官能不对称催化剂的新条目：吡啶衍生物的催化对映选择性的反应

Catalytic asymmetric domino Michael-Henry reaction: Enantioselective access to bicycles with consecutive quaternary ceuters by using bifunctional catalysts

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