Chemoenzymatic dynamic kinetic resolution of axially chiral alienes

B?ckvall J.-E.; Deska J.; Del Pozo Ochoa C.

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Chemoenzymatic dynamic kinetic resolution of axially chiral alienes

机译：轴向手性异体的化学酶动力学动力学解析

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(Chemical Equation Presented) At the palladium: Dimeric palladium bromide complexes bearing monodentate N-heterocyclic carbene ligands have been identified as efficient catalysts for the chemoselective racemization of axially chiral allenyl alcohols. In combination with porcine pancreatic lipase as biocatalyst, a dynamic kinetic resolution has been developed, giving access to optically active alienes in good yield and high enantiomeric purity (see scheme).

机译：（呈现的化学方程式）在钯上：具有单齿N-杂环卡宾配体的二聚溴化钯络合物已被鉴定为轴向手性烯基醇化学选择性外消旋的有效催化剂。结合猪胰脂肪酶作为生物催化剂，已开发出动态动力学拆分方法，可以以高收率和高对映体纯度获得旋光性异戊二烯（参见方案）。

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《Chemistry: A European journal》 |2010年第15期|共5页
作者
B?ckvall J.-E.; Deska J.; Del Pozo Ochoa C.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
Allenes; Biocatalysis; Dynamic kinetic resolution; Palladium; Racemization;

机译：丙二烯;生物催化;动态动力学拆分;钯;吸附;

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1. Chemoenzymatic dynamic kinetic resolution of axially chiral alienes [J] . B?ckvall J.-E., Deska J., Del Pozo Ochoa C. Chemistry: A European journal . 2010,第15期

机译：轴向手性异体的化学酶动力学动力学解析
2. Hydrogen-Bond-Enabled Dynamic Kinetic Resolution of Axially Chiral Amides Mediated by a Chiral Counterion [J] . Fugard Alison J., Lahdenpera Antti S. K., Tan Jaqueline S. J., Angewandte Chemie . 2019,第9期

机译：通过手性反驳介导的轴向手性酰胺的氢键能动态动态分辨率
3. Lipase-Catalyzed Dynamic Kinetic Resolution of C-1- and C-2-Symmetric Racemic Axially Chiral 2,2 '-Dihydroxy-1,1 '-biaryls [J] . Moustafa Gamal A. I., Oki Yasuhiro, Akai Shuji Angewandte Chemie . 2018,第32期

机译：脂肪酶催化的C-1和C-2 - 对称外消旋轴向手性2,2'-DiHydroxy-1,1'架的动态动力学分辨率
4. Kinetic Resolution of Axially Chiral 1-Arylnaphthalenes throughthe Arene Hydrogenation with Chiral Ruthenium Catalyst [C] . Sungyong Won, Yushu Jin, Ryoichi Kuwano 日本化学会春季年会 . 2020

机译：通过用手性钌催化剂芳烃氢化轴向手性1-芳基萘的动力学分辨率
5. Chiral substituted bicyclic lactam templates through cyclocondensation reactions of gamma-oxo-acids and aminoalcohols: The affect of substituents on enantiomeric ratio due to dynamic kinetic resolution. [D] . Jenkins, Crystal F. 2011

机译：通过γ-氧代酸和氨基醇的环缩合反应手性取代的双环内酰胺模板：由于动态动力学拆分，取代基对对映体比率的影响。
6. Hydrogen‐Bond‐Enabled Dynamic Kinetic Resolution of Axially Chiral Amides Mediated by a Chiral Counterion [O] . Dr. Alison J. Fugard, Dr. Antti S. K. Lahdenperä, Dr. Jaqueline S. J. Tan, -1

机译：氢键使手性平衡离子介导的轴向手性酰胺动态动力学拆分
7. Hydrogen‐Bond‐Enabled Dynamic Kinetic Resolution of Axially Chiral Amides Mediated by a Chiral Counterion [O] . Alison J. Fugard, Antti S. K. Lahdenperä, Jaqueline S. J. Tan, 2019

机译：通过手性反驳介导的轴向手性酰胺的氢键能动态动态动力分辨率

Chemoenzymatic dynamic kinetic resolution of axially chiral alienes

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