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A scanning probe microscopy study of annulated redox-active molecules at a liquid/solid interface: The overruling of the alkyl chain paradigm

机译:液体/固体界面上环状氧化还原活性分子的扫描探针显微镜研究:烷基链范式的否决

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摘要

(Figure Presented) Overruled! The self-assembly of a novel group of fused donor-acceptor molecules (1) comprising hexaazatriphenylene and tetrathiafulvalene branches was studied by STM at the liquid/solid interface. A 2D assembled chiral porous network with C_3 symmetry was found, which is dictated by strong interactions of the extended π-conjugated cores of the fused units with the HOPG substrate overruling the directional forces of alkyl chains.
机译:(已呈现图)否决了! STM在液/固界面处研究了一组新的含六氮杂三苯并四硫富瓦烯支链的稠合供体-受体分子(1)的自组装。发现具有C_3对称性的二维组装手性多孔网络,这是由熔融单元的扩展π共轭核与HOPG底物的强相互作用强于烷基链的定向力所决定的。

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