Hg(OTf)_2-BINAPHANE-catalyzed enantioselective anilino sulfonamide allyl alcohol cyclization

Yamamoto H.; Ho E.; Namba K.; Imagawa H.; Nishizawa M.

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Hg(OTf)_2-BINAPHANE-catalyzed enantioselective anilino sulfonamide allyl alcohol cyclization

机译：Hg（OTf）_2-联胺催化的对映选择性苯胺磺酰胺烯丙醇环化

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摘要

Chiral ligands: Hg(OTf)_2-catalyzed cyclization of anilino sulfonamide allyl alcohol is described; this reaction gives 2-vinyl indoline derivatives in good yields and excellent enantioselectivity by using a chiral BINAPHANE ligand (see scheme).

机译：手性配体：描述了Hg（OTf）_2催化苯胺磺酰胺烯丙醇的环化;通过使用手性BINAPHANE配体（参见方案），该反应可得到高收率和出色的对映选择性的2-乙烯基二氢吲哚衍生物。

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《Chemistry: A European journal》 |2010年第37期|共4页
作者
Yamamoto H.; Ho E.; Namba K.; Imagawa H.; Nishizawa M.;
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正文语种 eng
中图分类应用化学;
关键词
Alcohols; Allylic compounds; Cyclization; Enantioselectivity; Mercury;

机译：醇;烯丙基化合物;环化;对映选择性;汞;

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1. Hg(OTf)_2-BINAPHANE-catalyzed enantioselective anilino sulfonamide allyl alcohol cyclization [J] . Yamamoto H., Ho E., Namba K., Chemistry: A European journal . 2010,第37期

机译：Hg（OTf）_2-联胺催化的对映选择性苯胺磺酰胺烯丙醇环化
2. Hg(OTf)₂–BINAPHANE-Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization [J] . Dr. Hirofumi Yamamoto, Elisabeth Ho, Dr. Kosuke Namba, Chemistry - A European Journal . 2010,第37期

机译：Hg（OTf）_{2 -联萘烷催化的对映选择性苯胺磺酰胺烯丙基醇环化反应}
3. Hg(OTf)(2)-catalyzed cyclization of N-tosylanilinoallylic alcohols to 2-vinylindolines [J] . Namba K, Nakagawa Y, Yamamoto H, Synlett . 2008,第11期

机译：Hg（OTf）（2）催化的N-甲苯磺酸烯丙基醇成环化成2-vinylindolines
4. Effective Hydroalkoxylation/Cyclization of Alkynyl Alcohol Catalyzed by ln(OTf)_3 [C] . ZHANG Jian-Ting, ZHU Cheng-Lin, FENG Jun-Min International Conference on Chemical Engineering and Advanced Materials . 2014

机译：用LN（OTF）_3催化催化的炔基醇的有效的水烷氧基化/环化
5. 1. Development of palladium-catalyzed aerobic oxidative amination of alkenes 2. Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands [D] . McDonald, Richard I. 2010

机译：1.开发钯催化的烯烃的好氧氧化胺化2.使用手性二氮杂正膦配体对N-乙烯基羧酰胺，烯丙基氨基甲酸酯和烯丙基醚进行对映选择性加氢甲酰化
6. Toward Palau’amine: Hg(OTf)2-Catalyzed Allyl Alcohol Cyclization of Acylhydrazide to Construct the Cyclopentane Core [O] . Kosuke Namba, Yukari Kaihara, Hirofumi Yamamoto, -1

机译：向帕劳的酰胺：Hg（OTF）2催化酰肼的烯丙基醇环化以构建环戊烷核心
7. Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate [O] . In Su Kim, Ming-Yu Ngai, Michael J. Krische 2008

机译：使用烯丙基乙酸酯作为烯丙基金属替代物，从醇或醛氧化水平的对糖尿病或醛氧化水平的酶催化羰基烯丙胺
8. NTP Technical Report on the Comparative Toxicity Studies of Allyl Acetate, Allyl Alcohol, and Acrolein (CAS NOS. 591-87-7, 107-18-6, and 107-02-8) Administered by Gavage to F344/N Rats and B6C3F(sub 1) Mice. [R] . 2006

机译：关于乙酸烯丙酯，烯丙醇和丙烯醛的比较毒性研究的NTp技术报告（Cas NOs.591-87-7,107-18-6和107-02-8）通过管饲法给予F344 / N大鼠和B6C3F （小1）小鼠。

Hg(OTf)_2-BINAPHANE-catalyzed enantioselective anilino sulfonamide allyl alcohol cyclization

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