Application of Copper(II)-Dipyridylphosphine Catalyst in the Asymmetric Hydrosilylation of Simple Ketones in Air

Zhang XC; Wu Y; Yu F; Wu FF; Wu J; Chan ASC

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Application of Copper(II)-Dipyridylphosphine Catalyst in the Asymmetric Hydrosilylation of Simple Ketones in Air

机译：铜（II）-二吡啶膦催化剂在空气中简单酮的不对称氢化硅烷化中的应用

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摘要

The asymmetric hydrosilylation of prochiral ketones mediated by chiral copper catalysts as a desirable approach toward nonracemic secondary alcohols has recently gained considerable attention,[1] owing to the advantages of the inexpensive metal, mild reaction conditions, and operational simplicity.

机译：由于廉价的金属，温和的反应条件和操作简便的优点，由手性铜催化剂介导的前手性酮的不对称氢化硅烷化作为制备非外消旋仲醇的一种理想方法最近受到了广泛的关注[1]。

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《Chemistry: A European journal》 |2009年第24期|共4页
作者
Zhang XC; Wu Y; Yu F; Wu FF; Wu J; Chan ASC;
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正文语种 eng
中图分类应用化学;
关键词
Application; Copper(II)-Dipyridylphosphine; Simple Ketones;

机译：用途;铜（II）-联吡啶膦;简单酮;

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专利

1. Application of Copper(II)-Dipyridylphosphine Catalyst in the Asymmetric Hydrosilylation of Simple Ketones in Air [J] . Zhang XC, Wu Y, Yu F, Chemistry: A European journal . 2009,第24期

机译：铜（II）-二吡啶膦催化剂在空气中简单酮的不对称氢化硅烷化中的应用
2. Cobalt(II)-catalyzed asymmetric hydrosilylation of simple ketones using dipyridylphosphine ligands in air [J] . Feng Yu, Xi-Chang Zhang, Fei-Fei Wu, Organic & biomolecular chemistry . 2011,第16期

机译：使用二吡啶基膦配体在空气中钴（II）催化简单酮的不对称氢化硅烷化
3. Copper-Dipyridylphosphine-Polymethylhydrosiloxane: A Practical and Effective System for the Asymmetric Catalytic Hydrosilylation of Ketones [J] . Xi-Chang Zhang, Fei-Fei Wu, Shijun Li Advanced synthesis & catalysis . 2011,第9期

机译：铜-二吡啶基膦-聚甲基氢硅氧烷：酮的不对称催化氢化硅烷化的实用有效体系
4. Synthesis of Rh(III) Complexes Having a Disilacyclic Skeleton, and Catalytic Hydrosilylation of Ketones [C] . Yusuke Sunada, Yoshiki Fujimura, Hideo Nagashima Symposium on Organometallic Chemistry . 2007

机译：具有白硅骨架的RH（III）复合物的合成，酮催化氢化硅烷化
5. Part I. Asymmetric hydrosilylation of acetophenone using titanium catalysts. Part II. Synthesis of water-soluble palladacycles and their applications to the Suzuki reaction. Part III. Rhodium-catalyzed addition of aryl and alkenylboronic acids to aldehyde [D] . Huang, Rongcai. 2005

机译：第一部分：使用钛催化剂的苯乙酮不对称氢化硅烷化。第二部分水溶性palladacycles的合成及其在铃木反应中的应用。第三部分铑催化的芳基和烯基硼酸加成醛
6. A remarkably effective copper(II)-dipyridylphosphine catalyst system for the asymmetric hydrosilylation of ketones in air [O] . Jing Wu, Jian-Xin Ji, Albert S. C. Chan 2005

机译：一种非常有效的铜（II）-二吡啶基膦催化剂体系用于空气中酮的不对称氢化硅烷化
7. Application of copper(II)-dipyridylphosphine catalyst in the asymmetric hydrosilylation of simple ketones in air [O] . Zhang XC, Wu Y, Yu F, 2009

机译：铜（II）-二吡啶膦催化剂在空气中简单酮的不对称氢化硅烷化中的应用

Application of Copper(II)-Dipyridylphosphine Catalyst in the Asymmetric Hydrosilylation of Simple Ketones in Air

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