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首页> 外文期刊>Chemistry: A European journal >Squaramides: Bridging from molecular recognition to bifunctional organocatalysis
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Squaramides: Bridging from molecular recognition to bifunctional organocatalysis

机译：方胺：从分子识别到双功能有机催化的桥梁

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摘要

In this minireview, squaramides are presented from their roots as artificial anion receptors in molecular recognition studies to their recent advances as powerful bifunctional hydrogen-bonding catalysts in asymmetric organocatalysis. The main features of the squaramido functionality and the direct comparison with the analogous ureas and thioureas are also discussed. New dimensions for squaramides: In this minireview, squaramides are presented from their roots as artificial anion receptors in molecular recognition studies to the new advances in their application in asymmetric organocatalysis as powerful bifunctional hydrogen-bonding catalysts. The main features of the squaramido functionality and direct comparison with analogous ureas and thioureas are also discussed.
机译：在本篇综述中，对角酰胺从分子识别研究中的人工阴离子受体的根源到其在不对称有机催化中作为强大的双官能氢键催化剂的最新进展提出。还讨论了方酸官能度的主要特征以及与类似脲和硫脲的直接比较。方酸酰胺的新尺寸：在本微型综述中，方酸酰胺从分子识别研究中的人工阴离子受体的根源到其在不对称有机催化中作为强大的双官能氢键催化剂的应用新进展。还讨论了方酸官能度的主要特征以及与类似尿素和硫脲的直接比较。

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