Synthetic design of heterometallic cluster compounds with site-selective and stepwise substitution of bridging carboxylates

Ikegami A.; Abe M.; Inatomi A.; Hisaeda Y.

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Synthetic design of heterometallic cluster compounds with site-selective and stepwise substitution of bridging carboxylates

机译：具有桥碳酸盐的位点选择和逐步取代的异金属簇化合物的合成设计

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At the right places: Owing to substitution-lability difference in disparate metal centers, an oxo-centered heterometallic trinuclear acetato complex [Ru_2MgO(CH_3COO)_6(Py)_3] (py=pyridine; see picture) undergoes site-selective substitution of propionates and ferrocenycarboxylates in a stepwise manner. The new substituted families have been successfully separated by chromatography and fully characterized. (Chemical Figure Presented)

机译：在正确的地方：由于不同金属中心的取代稳定性不同，以羰基为中心的异金属三核乙酰丙酮络合物[Ru_2MgO（CH_3COO）_6（Py）_3]（py = pyridine;见图）进行了丙酸的位点选择性取代和二茂铁羧酸盐逐步地形成。新的取代家族已通过色谱法成功分离并进行了充分表征。（呈现化学图）

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《Chemistry: A European journal》 |2010年第15期|共4页
作者
Ikegami A.; Abe M.; Inatomi A.; Hisaeda Y.;
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正文语种 eng
中图分类应用化学;
关键词
Carboxylates; Cluster compounds; Coordination chemistry; Ruthenium; Substitution reactions;

机译：羧酸盐;簇合物;配位化学;钌;取代反应;

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1. Synthetic design of heterometallic cluster compounds with site-selective and stepwise substitution of bridging carboxylates [J] . Ikegami A., Abe M., Inatomi A., Chemistry: A European journal . 2010,第15期

机译：具有桥碳酸盐的位点选择和逐步取代的异金属簇化合物的合成设计
2. Nonemployed Simple Carboxylate Ions in Well-Investigated Areas of Heterometallic Carboxylate Cluster Chemistry: A New Family of {Cu(4)(II)Ln(8)(III)} Complexes Bearing tert-Butylacetate Bridging Ligands [J] . Dermitzaki Despina, Raptopoulou Catherine P., Psycharis Vassilis, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2015,第15期

机译：未充分研究的杂金属羧酸盐簇化学领域中的未使用的简单羧酸盐离子：{Cu（4）（II）Ln（8）（III）}络合物的新家族，带有乙酸叔丁酯桥联配体
3. On the Question of Site-Selective Ligand Exchange in Carboxylate-Substituted Metal Oxo Clusters [J] . Kreutzer Johannes, Czakler Matthias, Puchberger Michael, European journal of inorganic chemistry . 2015,第17期

机译：关于羧酸取代的金属氧簇中的位点选择性配体交换问题
4. Carboxylate-Substituted Oxotitanium and Oxozirconium Clusters as Structural Models for Titania- and Zirconia-Based Inorganic-Organic Hybrid Materials [C] . Guido Kickelbick, Ulrich Schubert Organic/Inorganic hybrid materials . 1998

机译：羧酸取代的氧钛和氧锆簇作为基于二氧化钛和氧化锆的无机有机杂化材料的结构模型
5. Synthetic, mechanistic, and structural studies of polynuclear metal clusters and hydrazido-substituted tantalum(v) compounds [D] . Huang, Shih-huang 2010

机译：多核金属团簇和肼基取代钽（v）化合物的合成，机理和结构研究
6. On the Question of Site-Selective Ligand Exchange in Carboxylate-Substituted Metal Oxo Clusters [O] . Johannes Kreutzer, Matthias Czakler, Michael Puchberger, -1

机译：关于羧酸取代的金属氧簇中的位点选择性配体交换问题
7. Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe2 oxo-acetylide cluster compounds [O] . CHI Y 2011

机译：杂金属羰基簇氧化物。 WRe2氧-乙炔簇化合物的形成，结构和反应活性

Synthetic design of heterometallic cluster compounds with site-selective and stepwise substitution of bridging carboxylates

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