First Generation and Trapping of a Dehydrometallophthalocyanine Starting from Triazole-Functionalized Zinc Phthalocyanine

Sergei I.Vagin; Antje Frickenschmidt; Bernd Kammerer; Michael Hanack

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First Generation and Trapping of a Dehydrometallophthalocyanine Starting from Triazole-Functionalized Zinc Phthalocyanine

机译：从三唑官能化酞菁锌开始的第一代脱氢金属酞菁捕获

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Direct 1N-amination of the triazole-fused zinc phthalocyanine 2 and oxidation of the formed amino derivative 3 resulted in the generation of the very reactive intermediate,the de-hydrometallophthalocyanine 4,which was not known previously.The latter was trapped in situ with different dienes,for example,furan,tetraphenyl-cyclopentadienone,and anthracene to form the corresponding Diels-Alder adducts.The products were characterized by ~1H and ~(13)C-deptl35 NMR,and UV/Vis spectroscopy,MALDI-TOF mass spectrometry,and elemental analysis,which are fully in agreement with their structure.The developed synthetic procedure opens a simple and versatile pathway towards unsymmetrical peripheral modification of phthalocya-nines,which is readily applicable to the micromol scale and is important for the design of new interesting Pc-based systems.

机译：三唑稠合的酞菁锌2的直接1N胺化反应以及所形成的氨基衍生物3的氧化反应导致生成了非常活泼的中间体，即氢加氢酞菁4，该中间体以前是未知的。二呋喃，呋喃，四苯基-环戊二烯酮和蒽形成相应的Diels-Alder加合物。产物的特征在于〜1H和〜（13）C-deptl35 NMR，UV / Vis光谱，MALDI-TOF质谱，以及元素分析，这与它们的结构完全吻合。发达的合成方法为邻苯二甲腈的不对称外围修饰开辟了一条简单而通用的途径，该途径易于应用于小分子规模，对于设计新的有趣分子很重要。基于PC的系统。

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《Chemistry: A European journal》 |2005年第22期|共6页
作者
Sergei I.Vagin; Antje Frickenschmidt; Bernd Kammerer; Michael Hanack;
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正文语种 eng
中图分类化学;
关键词
cycloaddition; dehydrometallophthalocyanine; phthalocyanines; spectroscopic properties; zinc;

机译：环加成;脱氢金属酞菁;酞菁;光谱性质;锌;

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1. First Generation and Trapping of a Dehydrometallophthalocyanine Starting from Triazole-Functionalized Zinc Phthalocyanine [J] . Sergei I.Vagin, Antje Frickenschmidt, Bernd Kammerer, Chemistry: A European journal . 2005,第22期

机译：从三唑官能化酞菁锌开始的第一代脱氢金属酞菁捕获
2. Photofunctional Polyurethane Nanofabrics Doped by Zinc Tetraphenylporphyrin and Zinc Phthalocyanine Photosensitizers [J] . Mosinger J, Lang K, Kubat P, Journal of Fluorescence . 2009,第4期

机译：四苯基卟啉锌和酞菁锌光敏剂掺杂的光功能聚氨酯纳米织物
3. Photofunctional Polyurethane Nanofabrics Doped by Zinc Tetraphenylporphyrin and Zinc Phthalocyanine Photosensitizers [J] . Mosinger J, Lang K, Kubat P, Journal of Fluorescence . 2009,第4期

机译：四苯基卟啉锌和酞菁锌光敏剂掺杂的光功能聚氨酯纳米织物
4. Femtosecond measurement of the third order nonlinear optical coefficients of CuPc (copper phthalocyanine), CoPc (cobalt phthalocyanine) and ZnPc (zinc phthalocyanine) thin films using Z-scan measurement method [C] . Shin, M.J., Wu, . 1999

机译：飞秒测量ZP扫描法测量CuPc（铜酞菁），CoPc（钴酞菁）和ZnPc（锌酞菁）薄膜的三阶非线性光学系数
5. Trap states dependence on morphology of zinc phthalocyanine thin films. [D] . Karadayi, Alev Eren. 2011

机译：陷阱状态取决于锌酞菁薄膜的形态。
6. Biological activities of phthalocyanines--XVI. Tetrahydroxy- and tetraalkylhydroxy zinc phthalocyanines. Effect of alkyl chain length on in vitro and in vivo photodynamic activities. [O] . R. W. Boyle, C. C. Leznoff, J. E. van Lier 1993

机译：酞菁的生物活性-XVI。四羟基和四烷基羟基锌酞菁。烷基链长度对体外和体内光动力活性的影响。
7. Synthesis and Characterization of a Novel Frétchet Dendritic Phthalocyanine Zinc(II): Tetra-{3,5-di-3,5-di-(4-carboxylic benzyloxy)benzyloxybenzyloxy} Phthalocyanine Zinc(Ⅱ) [O] . 贺丹丹, 张宏, 彭亦如, 2012

机译：新型弗雷切特树枝状酞菁锌（II）的合成与表征：四-{3,5-二-3,5-二-（4-羧基苄氧基）苄氧基苄氧基}酞菁锌（Ⅱ）

First Generation and Trapping of a Dehydrometallophthalocyanine Starting from Triazole-Functionalized Zinc Phthalocyanine

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