Synthesis of large ring macrocycles (12-18) by recyclable palladium-complexed dendrimers on silica gel catalyzed intramolecular cyclocarbonylation reactions

Lu SM; Alper H

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Synthesis of large ring macrocycles (12-18) by recyclable palladium-complexed dendrimers on silica gel catalyzed intramolecular cyclocarbonylation reactions

机译：硅胶催化分子内环羰基化反应中可回收钯复合树枝状大分子合成大环大环（12-18）

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Intramolecular cyclocarbonylation reactions with palladium-complexed dendrimers on silica gel as catalysts are very effective for the synthesis of twelve-to eighteen-membered ring macrocycles. This process can tolerate a wide variety of functional groups, including halide, ether, ketone, and ester. The heterogeneous dendritic catalysts facilitate excellent substrate reactivity, affording oxygen-, nitrogen-, or sulfur-containing tricyclic heterocycles in 70-92% yields. Importantly, these systems are easily recovered by simple filtration and reused several times with only a slight loss of activity.

机译：用钯配合物的树枝状大分子在硅胶上作为催化剂的分子内环羰基化反应对于合成十二至十八元环大环非常有效。该过程可以耐受多种官能团，包括卤化物，醚，酮和酯。非均相的树枝状催化剂促进了优异的底物反应性，以70-92％的收率提供了含氧，氮或硫的三环杂环。重要的是，这些系统很容易通过简单的过滤就可以回收，并可以重复使用几次，而只损失少量活性。

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《Chemistry: A European journal》 |2007年第20期|共9页
作者
Lu SM; Alper H;
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正文语种 eng
中图分类化学;
关键词
carbonylation; dendrimers; heterocycles; heterogeneous catalysis; palladium; ENCAPSULATED PD NANOPARTICLES; CARBOSILANE DENDRIMERS; HYDROFORMYLATION REACTIONS; ASYMMETRIC HYDROGENATION; HETEROCYCLIC-COMPOUNDS; RECOVERABLE CATALYSTS; HOMOGENEOUS CATALYSIS; DENDRITIC CATALYSTS; CLOSING METATHESIS; ORGANIC-SYNTHESIS;

机译：羰基化;树枝状大分子;杂环;非均相催化;钯;包封的PD纳米颗粒;碳硅烷二烯;加氢甲酰化反应;不对称加氢;杂环化合物;可回收的催化剂;均相;

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1. Synthesis of large ring macrocycles (12-18) by recyclable palladium-complexed dendrimers on silica gel catalyzed intramolecular cyclocarbonylation reactions [J] . Lu SM, Alper H Chemistry: A European journal . 2007,第20期

机译：硅胶催化分子内环羰基化反应中可回收钯复合树枝状大分子合成大环大环（12-18）
2. Intramolecular Carbonylation Reactions with Recyclable Palladium-Complexed Dendrimers on Silica:Synthesis of Oxygen,Nitrogen,or Sulfur-Containing Medium Ring Fused Heterocycles [J] . Shui-Ming Lu, Howard Alper Journal of the American Chemical Society . 2005,第42期

机译：可回收的钯复合树枝状大分子在二氧化硅上的分子内羰基化反应：氧，氮或含硫的中环熔融杂环的合成
3. Synthesis of unsaturated seven-membered ring lactams through palladium-catalyzed amination and intramolecular cyclocarbonylation reactions of amines and Baylis-Hillman acetates [J] . Cao H., Vieira T.O., Alper H. Organic letters . 2011,第1期

机译：通过钯和胺与Baylis-Hillman乙酸酯的钯催化胺化和分子内环羰基化反应合成不饱和七元环内酰胺
4. Activation of amine-catalyzed nitroaldol reactions by silica gel or SBA-15 [C] . Kiyoshi Tanemura 日本化学会春季年会講演予稿集 . 2018

机译：硅胶或SBA-15激活胺催化的硝基甲醇反应
5. 1. Axially-chiral 7-membered N-heterocyclic carbenes: Synthesis and application to palladium-catalyzed intramolecular aerobic oxidation of olefins 2. Development of palladium-catalyzed aerobic oxidative olefin amination reactions [D] . Scarborough, Christopher C. 2008

机译：1.轴向手性7元N-杂环卡宾：烯烃的钯催化分子内需氧氧化的合成及应用2.钯催化需氧氧化烯烃胺化反应的发展
6. Enantioselective Synthesis of 57-Bicyclic Ring Systems from Axially Chiral Allenes Using a Rh(I)-Catalyzed Cyclocarbonylation Reaction [O] . Francois Grillet, Kay M. Brummond -1

机译：使用Rh（I）催化的环羰基化反应从轴向手性异戊烯对映选择性合成57-双环系统
7. Selective Reactions Catalyzed by Silica Gel-Supported Sulfates and Oxidation Using Silica Gel-Supported Nitrates. Organic Synthesis on Solid Surface. [O] . Takeshi NISHIGUCHI 1993

机译：使用硅胶负载硫酸盐催化的选择性反应和使用硅胶负载的硝酸盐氧化。固体表面上的有机合成。

Synthesis of large ring macrocycles (12-18) by recyclable palladium-complexed dendrimers on silica gel catalyzed intramolecular cyclocarbonylation reactions

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