Hole transfer rates in A-form DNA/2 '-OMeRNA hybrid

Kawai K; Osakada Y; Sugimoto A; Fujitsuka M; Majima T

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Hole transfer rates in A-form DNA/2 '-OMeRNA hybrid

机译：A型DNA / 2'-OMeRNA杂种的空穴转移率

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The hole transfer rates in the DNA/DNA B-form duplex and DNA/2'-OMeRNA A-form duplex were measured which occurred in the time range of approximate to 100 mu s. The hole transfer rates in the A-form duplexes were slower and more strongly dependent on the temperature compared to those in the B-form duplexes, suggesting that the A-form is more rigid than the B-form duplex in this time scale.

机译：测量在大约100μs的时间范围内发生的DNA / DNA B-型双链体和DNA / 2'-OMeRNA A-型双链体中的空穴转移速率。与B型双工中的空穴传输速率相比，A型双工中的空穴传输速率更慢，并且对温度的依赖性更强，这表明在此时间范围内，A型比B型双工具有更高的刚性。

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《Chemistry: A European journal》 |2007年第8期|共6页
作者
Kawai K; Osakada Y; Sugimoto A; Fujitsuka M; Majima T;
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正文语种 eng
中图分类化学;
关键词
charge transfer; DNA structures; DNA; RNA; transient absorption; CHARGE-SEPARATED STATE; DNA-RNA HYBRID; RADICAL-CATION; ELECTRON-TRANSFER; TRANSCRIPTIONAL REPRESSION; STRUCTURAL FLUCTUATIONS; DISTANCE DEPENDENCE; PULSE-RADIOLYSIS; DUPLEX DNA; DYNAMICS;

机译：电荷转移;DNA结构;DNA;RNA;瞬时吸收;电荷分离状态;DNA-RNA杂化;自由基阳离子;电子转移;转录阻抑;结构波动;距离依赖性;脉冲辐射分解;双链DNA;动力学;

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专利

1. Hole transfer rates in A-form DNA/2 '-OMeRNA hybrid [J] . Kawai K, Osakada Y, Sugimoto A, Chemistry: A European journal . 2007,第8期

机译：A型DNA / 2'-OMeRNA杂种的空穴转移率
2. Charge-transfer matrix elements by FMO-LCMO approach: Hole transfer in DNA with parameter tuned range-separated DFT [J] . Kitoh-Nishioka Hirotaka, Ando Koji Chemical Physics Letters . 2015,第Null期

机译：通过FMO-LCMO方法进行的电荷转移基质元素：通过参数调整的距离分隔DFT在DNA中进行空穴转移
3. Accurate length determination of DNA molecules visualized by atomic force microscopy: evidence for a partial B-to A-form transition on mica [J] . Claudio Rivetti, Simone Codeluppi Ultramicroscopy . 2001,第1a2期

机译：通过原子力显微镜观察DNA分子的准确长度测定：云母上部分B到A形式转变的证据
4. Hole-transfer Mechanism in Hydrated DNA Duplexes: Direct Ab Initio Molecular Dynamics Simulation [C] . H. Wakabayashi, Y. Ishikawa, T. Tsukamoto, ECS Meeting/PRiME . 2009

机译：水合DNA双链体中的空穴传输机制：DIAMING AB ININIO分子动力学模拟
5. Charge transfer in DNA: Effects of humidity and molecular vibrations on detection and rate of hole transport. [D] . Leveritt, John M., III. 2013

机译：DNA中的电荷转移：湿度和分子振动对检测和空穴传输速率的影响。
6. Hole Transport in A-form DNA/RNA Hybrid Duplexes [O] . Jiun Ru Wong, Fangwei Shao -1

机译：A型DNA / RNA杂交双链体中的空穴传输
7. Hole Transport in A-form DNA/RNA Hybrid Duplexes [O] . Jiun Ru Wong, Fangwei Shao 2017

机译：A形DNA / RNA混合双链体中的空穴传输

Hole transfer rates in A-form DNA/2 '-OMeRNA hybrid

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