Synthesis and Structures of Trifluoromethyl-, Fluoro-, and Azido-Substituted Hexabenzylhexaazaisowurtzitanes and IsolAtion of a Novel Hexaazaisowurtzitane-Based Polycycle

Thomas M.Klapotke; Burkhard Krumm; Holger Piotrowski; Kurt Polborn; Gerhard Holl

首页> 外文期刊>Chemistry: A European journal >Synthesis and Structures of Trifluoromethyl-, Fluoro-, and Azido-Substituted Hexabenzylhexaazaisowurtzitanes and IsolAtion of a Novel Hexaazaisowurtzitane-Based Polycycle

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Synthesis and Structures of Trifluoromethyl-, Fluoro-, and Azido-Substituted Hexabenzylhexaazaisowurtzitanes and IsolAtion of a Novel Hexaazaisowurtzitane-Based Polycycle

机译：三氟甲基，氟和叠氮基取代的六苄基六氮杂异纤锌矿型结构化合物的合成，结构和基于六氮杂异纤锌矿型结构的新型多环化合物的分离

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The first hexabenzylhexaazaisowurtzitane cage compounds with trifluoromethyl and azide groups, as well as those with fluorine atoms in the 3-and 4-positions, have been prepared and fully characterized. A study of the substituent influence on the benzene ring regarding the formation of the hexaazaisowurtzitane polcycle in either the 2-or 4-position with CF_3, F, and N_3 revealed an interesting difference. In all cases with CF_3, F, and N_3 substituents in the 4-position, the corresponding hexabenzylhexaazaisowurtzitanes were isolated. The corresponding hexabenzylhexaazaisourtzitanes were also formed when these substituents were in the 2-position; however, in addition with azide in 2-position a novel type of polycycle was isolated and identified. ~15N NMR data and crystal structures of hexabenzylhexaazaisowurtzitane derivatives were obtained and are discussed in detail.

机译：已经制备并充分表征了具有三氟甲基和叠氮化物基团以及在3-和4-位具有氟原子的那些的第一六苄基六氮杂异纤锌矿型结构化合物。关于在CF_3，F和N_3的2位或4位上六氮杂异纤锌矿型结构环的形成对取代基对苯环的影响的研究显示出有趣的差异。在CF_3，F和N_3取代基在4-位的所有情况下，均会分离出相应的六苄基六氮杂异纤锌矿型结构烷烃。当这些取代基位于2-位时，也形成了相应的六苄基六氮杂异纤锌钛烷。然而，除了2位叠氮化物外，还分离并鉴定了一种新型的多环化合物。获得了〜15N NMR数据和六苄基六氮杂异纤锌矿型结构烷烃衍生物的晶体结构，并进行了详细讨论。

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来源
《Chemistry: A European journal》 |2003年第3期|共8页
作者
Thomas M.Klapotke; Burkhard Krumm; Holger Piotrowski; Kurt Polborn; Gerhard Holl;
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正文语种 eng
中图分类化学;应用化学;
关键词
azides; fluorine; NMR spectroscopy; polycycles; structure elucidation;

机译：叠氮化物;氟;NMR光谱;多环化合物;结构阐明;

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1. Synthesis and Structures of Trifluoromethyl-, Fluoro-, and Azido-Substituted Hexabenzylhexaazaisowurtzitanes and IsolAtion of a Novel Hexaazaisowurtzitane-Based Polycycle [J] . Thomas M.Klapotke, Burkhard Krumm, Holger Piotrowski, Chemistry: A European journal . 2003,第3期

机译：三氟甲基，氟和叠氮基取代的六苄基六氮杂异纤锌矿型结构化合物的合成，结构和基于六氮杂异纤锌矿型结构的新型多环化合物的分离
2. Isolation and characterization of 2'-fluoro-, 2'-amino-, and 2'-fluoro-/amino-modified RNA ligands to human IFN-gamma that inhibit receptor binding. [J] . M F Kubik, C Bell, T Fitzwater, The journal of immunology . 1997,第1期

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5. The Synthesis of Heteroatom-Containing Polycycles, Modulators of FtsZ, Isotopically Labeled Homocitric Acid Lactone, and Progress Towards Kibdelomycin and Amycolamicin. [D] . Moore, Jared T. 2014

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6. Crystal structure determination of two pyridine derivatives: 4-(E)-2-(4-methoxyphenyl)ethenyl-1-methylpyridin-1-ium hexafluoro-λ6-phosphane and 4-{(E)-2-4-(dimethylamino)phenylethenyl}-1-phenyl-1λ5-pyridin-1-ylium hexafluoro-λ6-phosphane [O] . J. Arul Martin Mani, M. Mercina, S. Antony Inglebert, 2019

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Synthesis and Structures of Trifluoromethyl-, Fluoro-, and Azido-Substituted Hexabenzylhexaazaisowurtzitanes and IsolAtion of a Novel Hexaazaisowurtzitane-Based Polycycle

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