Clays as a host matrix in the synthesis of organic macrocycles

Georgakilas V.; Gournis D.; Bourlinos AB.; Karakassides MA.; Petridis D.

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Clays as a host matrix in the synthesis of organic macrocycles

机译：粘土作为有机大环合成中的基质

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A new approach for the synthesis of amide macrocycles, based on the use of organo-clay derivatives as controlling template, is proposed as an alternative to the rotaxane method. Dications of p-xylylene diamine inserted in the clay interlayer space act as molding pillars around which neutral diamine molecules are erected via hydrogen bonding and pi - pi interactions to form supramolecular arrays. Condensation of diamines in the supramolecular arrays with diacetyl dichlorides yields various tetramide macrocycles in good yields. Shape, aromaticity and dimensions of the reactants are factors affecting the condensation reaction. [References: 27]

机译：提出了一种新的合成酰胺大环化合物的方法，该方法基于使用有机粘土衍生物作为控制模板，作为轮烷方法的替代方法。插入到粘土夹层空间中的对二甲苯二胺的阳离子充当模制柱，中性二胺分子通过氢键和pi-pi相互作用在其周围竖立，形成超分子阵列。超分子阵列中的二胺与二乙酰基二氯化物的缩合以良好的收率产生各种四酰亚胺大环。反应物的形状，芳香性和尺寸是影响缩合反应的因素。 [参考：27]

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《Chemistry: A European journal》 |2003年第16期|共5页
作者
Georgakilas V.; Gournis D.; Bourlinos AB.; Karakassides MA.; Petridis D.;
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正文语种 eng
中图分类化学;
关键词
Clays; Intercalations; Macrocycles; Supramolecular chemistry; Template synthesis; Catalysts; Montmorillonite; Rotaxanes;

机译：粘土;插层;大环化合物;超分子化学;模板合成;催化剂;蒙脱石;轮烷;

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1. Clays as a host matrix in the synthesis of organic macrocycles [J] . Georgakilas V., Gournis D., Bourlinos AB., Chemistry: A European journal . 2003,第16期

机译：粘土作为有机大环合成中的基质
2. Asymmetric mixed matrix membrane incorporating organically modified clay particle for gas separation [J] . A.K. Zulhairun, A.F. Ismail, T. Matsuura Chemical engineering journal . 2014,第Null期

机译：结合有机改性粘土颗粒的不对称混合基质膜用于气体分离
3. Donor-Acceptor Conjugated Macrocycles: Synthesis and Host-Guest Coassembly with Fullerene toward Photovoltaic Application [J] . Zhang Si-Qi, Liu Zhen-Yu, Fu Wei-Fei, ACS nano . 2017,第11期

机译：供体 - 受体共轭宏ycles：用富勒烯合成和宿主 - 客人朝向光伏应用
4. Synthesis and Characterization of an Organic-Inorganic Hybrid Nanocoating based on Polyacrylic-Silica (PAc-Si) as an Optical Host for Laser Dyes [C] . M. Ganjaee, M. Mohseni, Y. Aghili International Coatings Exposition . 2007

机译：基于聚丙烯酸二氧化硅（PAC-Si）作为激光染料光学宿主的有机 - 无机杂交纳米织物的合成与表征
5. Organic-inorganic hybrid mesoporous silica materials and their application as host matrix for protein molecules. [D] . Dong, Hua. 2002

机译：有机-无机杂化介孔二氧化硅材料及其作为蛋白质分子宿主基质的应用。
6. Organic Synthesis Toward Small-Molecule Probes and Drugs Special Feature: Fragment-based domain shuffling approach for the synthesis of pyran-based macrocycles [O] . Eamon Comer, Haibo Liu, Adrien Joliton, 2011

机译：面向小分子探针和药物的有机合成特殊功能：用于合成吡喃基大环化合物的基于片段的域改组方法
7. Synthesis of a Thirty Member Macrocycle for Use in Host-Guest Chemistry [O] . Lehuta Keith A., Roesner Faculty Advisor Rebecca 2011

机译：三十客体大环合成用于客体-客用化学
8. Direct synthesis of organic-containing clays and thermal analysis of porphyrin-clay complexes. [R] . K. A. Carrado K. B. Anderson P. S. Grutkoski 1991

机译：直接合成含有机物的粘土和卟啉 - 粘土配合物的热分析。

Clays as a host matrix in the synthesis of organic macrocycles

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