Enantioselective Borohydride Reduction Catalyzed by Optically Active Cobalt Complexes

Tohru Yamada; Takushi Nagata; Kiyoaki D.Sugi; Kiyotaka Yorozu; Taketo Ikeno; Yuhki Ohtsuka; Daichi Miyazaki; Teruaki Mukaiyama

首页> 外文期刊>Chemistry: A European journal >Enantioselective Borohydride Reduction Catalyzed by Optically Active Cobalt Complexes

【24h】

Enantioselective Borohydride Reduction Catalyzed by Optically Active Cobalt Complexes

机译：旋光钴配合物催化对映选择性硼氢化物的还原

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The highly enantioselective borohydride reduction of aromatic ketones or imines to the corresponding alcohols was developed in the presence of a catalytic amount of an optically active cobalt(II)complex catalyst.This enantioselective reduction is carried out using a precisely premodified borohydride with alcohols such as tetrahydrofurfuryl alcohol,ethanol and methanol.High optical yields are obtained by choosing the appropriate alcohol as modifiers and a suitable beta-ketoiminatoligand of the catalyst.The enantioselective borohydride reduction has been successfully applied to the preparation of optically active 1,3-diols,the stereoselective reduction of diacylferrocenes,and dynamic and/or kinetic resolution of 1,3-dicarbonyl compounds.

机译：在催化量的旋光钴（II）络合物催化剂的存在下，芳族酮或亚胺对映体的高度对映选择性硼氢化物得到了发展，这种对映选择性的还原是使用精确预修饰的硼氢化物与醇类（例如四氢糠基）进行的通过选择合适的醇作为改性剂和合适的催化剂β-酮亚氨基配体可以得到高的光学收率。对映选择性硼氢化物还原已成功地用于制备光学活性的1,3-二醇，立体选择性二酰基二茂铁的还原，以及1,3-二羰基化合物的动态和/或动力学拆分。

著录项

来源
《Chemistry: A European journal》 |2003年第18期|共25页
作者
Tohru Yamada; Takushi Nagata; Kiyoaki D.Sugi; Kiyotaka Yorozu; Taketo Ikeno; Yuhki Ohtsuka; Daichi Miyazaki; Teruaki Mukaiyama;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
asymmetric catalysis; diastereoselectivity; enantioselectivity; kinetic resolution; reduction;

机译：不对称催化;非对映选择性;对映选择性;动力学拆分;还原;

相似文献

外文文献
中文文献
专利

1. Dynamic Kinetic Resolution with Enantioselective Borohydride Reduction Catalyzed by Optically Active #beta#-Ketoiminato Cobalt(II) Complexes: Highly Diastereo-and Enantioselective Preparation of Optically Active anti-Aldol Compounds [J] . Yuhki Ohtsuka, Daichi Miyazaki, Taketo Ikeno, Chemistry Letters . 2002,第1期

机译：旋光性＃beta＃-酮氨基钴（II）配合物催化的对映选择性硼氢化物还原的动力学动力学拆分：光学活性抗醛醇化合物的高度非对映和对映选择性制备
2. Homogeneous Enantioselective Catalysis in a Continuous-Flow Microreactor: Highly Enantioselective Borohydride Reduction of Ketones Catalyzed by Optically Active Cobalt Complexes [J] . Takuo Hayashi, Satoshi Kikuchi, Yukako Asano Organic process research & development . 2012,第6期

机译：连续流微反应器中的均相对映选择性催化：旋光活性钴配合物催化酮的高对映选择性硼氢化还原
3. Enantioselective Borohydride Reduction Catalyzed by Optically Active Cobalt Complexes [J] . Tohru Yamada, Takushi Nagata, Kiyoaki D.Sugi, Chemistry: A European journal . 2003,第18期

机译：旋光钴配合物催化对映选择性硼氢化物的还原
4. Highly Active and Stereospecific Polymerization of 1,3-butadiene Catalyzed by Mono-or Di-nuclear Cobalt Complexes [C] . Pengfei Ai, Lin Chen, Yintian Guo, 7th international symposium on high-tech polymer materials: Synthesis, characterization and applications . 2012

机译：单或双核钴配合物催化1,3-丁二烯的高活性立体定向聚合
5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

机译：开发人造蛋白酶和核酸酶：催化水解未活化的酰胺，腈和磷酸盐。第一部分钴（III）配合物促进的磷酸酯的水解。第二部分钴（III）配合物催化的腈水合。第三部分钴（III）配合物促进的酰胺水解。
6. Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)Re(V)-Oxo Complexes [O] . Kristine A. Nolin, Richard W. Ahn, Yusuke Kobayashi, -1

机译：通过（CN-BOX）RE（V）-OxO复合物催化酮和癌症的致力选择性降低
7. Enantioselective Cyclopropanation Reaction Catalyzed by Optically Active Cobalt (II) Complexes and the Catalyst Design based on Theoretical Analysis [O] . Taketo Ikeno, Mitsuo Sato, Izumi Iwakura, 2008

机译：基于理论分析的光学活性钴（II）配合物催化催化致映选择性环丙烷反应及催化剂设计
8. Laboratory Studies of Hydrogen Gas Generation Using the Cobalt Chloride Catalyzed Sodium Borohydride-Water Reaction. [R] . Boss, P. A., Becker, C. A., Anderson, G. W., 2015

机译：用氯化钴催化硼氢化钠 - 水反应生成氢气的实验室研究。

Enantioselective Borohydride Reduction Catalyzed by Optically Active Cobalt Complexes

摘要

著录项

相似文献

相关主题

期刊订阅