[ReO_3(bipy)]~+[X]~--Catalyzded Aldehyde Olefination: Carbene and Phosphorane Intermediates

Xiangyang Zhang; Peter Chen

首页> 外文期刊>Chemistry: A European journal >[ReO_3(bipy)]~+[X]~--Catalyzded Aldehyde Olefination: Carbene and Phosphorane Intermediates

【24h】

[ReO_3(bipy)]~+[X]~--Catalyzded Aldehyde Olefination: Carbene and Phosphorane Intermediates

机译：[ReO_3（bipy）]〜+ [X]〜-催化的醛缩醛化：碳和磷烷中间体

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The aldehyde olefination reaction, catalyzed by cationic high-valent oxorhenium complexes, shows evidence of the intermediacy of both carbene complexes and phosphoranes. The solution-phase reaction is facile and amenable to tuning and is, hence, likely to prove to be of practical significance. Individual steps in the catalytic cycle are observed in the gas hase. Catalytic competence of each of the putative intermediates can be demonstrated.

机译：阳离子高价氧or络合物催化的醛烯化反应显示了卡宾络合物和磷烷的中间性证据。固溶相反应容易并且易于调整，因此很可能被证明具有实际意义。在汽油仓中观察到催化循环中的各个步骤。可以证明每种假定中间体的催化能力。

著录项

来源
《Chemistry: A European journal》 |2003年第8期|共8页
作者
Xiangyang Zhang; Peter Chen;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
carbene ligands; mass spectrometry; olefination; phosphoranes; reaction mechanisms; rhenium;

机译：卡宾配体;质谱;烯化;磷烷;反应机理;hen;

相似文献

外文文献
中文文献
专利

1. [ReO_3(bipy)]~+[X]~--Catalyzded Aldehyde Olefination: Carbene and Phosphorane Intermediates [J] . Xiangyang Zhang, Peter Chen Chemistry: A European journal . 2003,第8期

机译：[ReO_3（bipy）]〜+ [X]〜-催化的醛缩醛化：碳和磷烷中间体
2. [ReO3(bipy)](+)[X](-)-catalyzed aldehyde olefination: Carbene and phosphorane intermediates [J] . Zhang XY., Chen P. Chemistry: A European journal . 2003,第8期

机译：[ReO3（bipy）]（+）[X]（-）催化的醛烯化反应：碳和磷烷中间体
3. [ReO3(bipy)](+)[X](-)-catalyzed aldehyde olefination: Carbene and phosphorane intermediates [J] . Zhang XY., Chen P. Chemistry: A European journal . 2003,第8期

机译：[ReO3（bipy）]（+）[X]（-）催化的醛烯化反应：碳和磷烷中间体
4. Nickel(0)-Catalyzed Enantioselective Three-Component Coupling of 1,3-Dienes,Aldehydes,and Silanes Using Chiral N-Heterocyclic Carbenes as a Ligand [C] . Yn Hinata, Reiko Seki, Yoshihiro Oonishi Symposium on Organometallic Chemistry . 2007

机译：镍（0） - 使用手性N-杂环碳酸盐作为配体， - 催化1,3-二烯，醛和硅烷的映选择性三组分偶联
5. Studies of novel synthesis of functionalized polycyclic ring systems through the coupling reactions of Fischer carbene chromium complexes with enyne hydrazones and aldehydes. [D] . Ranchigoda Gamage, Lalith Santha. 2013

机译：通过Fischer卡宾铬络合物与烯炔和醛的偶联反应，对官能化多环系统进行新型合成的研究。
6. Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes [O] . Harit U. Vora, Philip Wheeler, Tomislav Rovis -1

机译：通过Nhetercyclic Carbene催化反应的α-Reducable醛的反应利用酰基和烯醇氮杂化合物
7. The stereochemistry of the Wittig reactions of allylic phosphoranes and phosphonate esters with aldehydes [O] . Richard Neville Gedye, Kenneth Charles Westaway, Parkash Arora, 1977

机译：醛磷酸磷酸磷酸酯和膦酸酯与醛的立体化学

[ReO_3(bipy)]~+[X]~--Catalyzded Aldehyde Olefination: Carbene and Phosphorane Intermediates

摘要

著录项

相似文献

相关主题

期刊订阅