Ionic Solid-State Dimers and Polymers Derived from Imidazolium Dicarboxylic Acids

Zhaofu Fei; Wee Han Ang; Tilmann J.Geldbach; Rosario Scopelliti; Paul J.Dyson

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Ionic Solid-State Dimers and Polymers Derived from Imidazolium Dicarboxylic Acids

机译：咪唑二羧酸衍生的离子型固态二聚体和聚合物

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A series of imidazolium dicarboxylic acids have been prepared from the reaction of the 1,3-bis(carboxymethyl)imidazolium zwit-terion with the Br0nsted acids HX(X=F,Br,Cl,ClO_4).The structures of these acids have been established in the solid state by single-crystal X-ray diffraction,which revealed that the cations and anions form strong hydrogen bonds through O-H-X interactions,leading to the formation of dimeric and polymeric networks.These acids react with elemental zinc and cobalt to form stable polymeric coordination complexes,some of which have also been characterised by X-ray diffraction.

机译：由1,3-双（羧甲基）咪唑鎓离子与布朗斯台德酸HX（X = F，Br，Cl，ClO_4）反应制得了一系列咪唑二羧酸。通过单晶X射线衍射确定固态，表明阳离子和阴离子通过OHX相互作用形成强大的氢键，导致形成二聚体和聚合物网络，这些酸与元素锌和钴反应形成稳定的聚合物配位配合物，其中一些也已通过X射线衍射表征。

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《Chemistry: A European journal》 |2006年第15期|共7页
作者
Zhaofu Fei; Wee Han Ang; Tilmann J.Geldbach; Rosario Scopelliti; Paul J.Dyson;
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正文语种 eng
中图分类化学;
关键词
Bronsted acids; coordination polymers; hydrogen bonds; ionic liquids; solid-state structures;

机译：布朗斯台德酸;配位聚合物;氢键;离子液体;固态结构;

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1. Ionic Solid-State Dimers and Polymers Derived from Imidazolium Dicarboxylic Acids [J] . Zhaofu Fei, Wee Han Ang, Tilmann J.Geldbach, Chemistry: A European journal . 2006,第15期

机译：咪唑二羧酸衍生的离子型固态二聚体和聚合物
2. Solid-state gel polymer electrolytes based on ionic liquids containing imidazolium cations and tetrafluoroborate anions for electrochemical double layer capacitors: Influence of cations size and viscosity of ionic liquids [J] . Pal P., Ghosh A. Journal of power sources . 2018,第DECa1期

机译：基于含咪唑鎓阳离子和四氟硼酸根阴离子的离子液体的固态凝胶聚合物电解质，用于电化学双层电容器：阳离子尺寸和离子液体粘度的影响
3. Hydrogen bonded binary molecular adducts derived from exobidentate N-donor ligand with dicarboxylic acids: Acid?imidazole hydrogen-bonding interactions in neutral and ionic heterosynthons [J] . Kathalikkattil A.C., Damodaran S., Bisht K.K., Journal of Molecular Structure . 2011,第2a3期

机译：明显的N-供体配体与二元羧酸的氢键二元分子加合物：中性和离子杂合子中的酸？咪唑氢键相互作用
4. Establishment of Electrical Equivalent Circuits from electrochemical impedance spectroscopy study of corrosion inhibition of steel by imidazolium derived ionic liquids in sulphuric acidic solution [C] . Perez-Navarrete J.-B. 2010 7th International Conference on Electrical Engineering Computing Science and Automatic Control . 2010

机译：从电化学阻抗谱研究建立等效电路，研究咪唑鎓离子液体在硫酸溶液中对钢的腐蚀抑制作用
5. Syntheses of PEG/alkyl-based imidazolium/pyridinium ionic liquids and applications on H2S absorption and syntheses of polysulfone based functionalized imidazolium ionic polymers and applications on gas separation. [D] . Zhang, Chengda. 2015

机译：PEG /烷基咪唑/吡啶离子液体的合成及其在H2S吸收中的应用和聚砜基官能化咪唑离子聚合物的合成及其在气体分离中的应用。
6. Synthesis Properties and Applications of Biodegradable Polymers Derived from Diols and Dicarboxylic Acids: From Polyesters to Poly(ester amide)s [O] . Angélica Díaz, Ramaz Katsarava, Jordi Puiggalí 2014

机译：多元醇和二元羧酸衍生的可生物降解聚合物的合成性能和应用：从聚酯到聚（酯酰胺）
7. Solid, Solution And Gas Phase Interactions Of An Imidazolium-based Task-specific Ionic Liquid Derived From Natural Kojic Acid [O] . Neto B.A.D., Mota A.A.R., Gatto C.C., 2015

机译：天然曲酸衍生的咪唑基特定任务离子液体的固相，溶液和气相相互作用

Ionic Solid-State Dimers and Polymers Derived from Imidazolium Dicarboxylic Acids

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