Pressure- and Temperature-Induced Phase Transition in 2,4,6-Trichloro-1,3,5-triazine Crystal

Makiko Tanaka; Chinatu Kariu; Yoshio Suzuki; Yoshinori Nibu; Ryoichi Shimada; Hiroko Shimada

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Pressure- and Temperature-Induced Phase Transition in 2,4,6-Trichloro-1,3,5-triazine Crystal

机译：2,4,6-三氯-1,3,5-三嗪晶体中压力和温度诱导的相变

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The effects of pressure and temperature on the frequencies and band structures of the Raman active inter- and in- tramolecular vibrations of 2,4,6-trichloro-1,3,5-traizine crystal were studied. The changes in the Raman frequency, band width, and band structure of both the inter- and intramolecular vibrations induced by changes of pressure and temperature indicate that (1) a displacive phase transition caused by a shear distortion of #pi#-stacked layer structure may take place under about 1.7 GPa at 298 K and (2) the intermolecular nitrogen-chlorine donor-acceptor attractive interactions sup-porting the extensive network structure in crystal have a direct effect upon the totally symmetric C-Cl stretching vibration.

机译：研究了压力和温度对2,4,6-三氯-1,3,5-traizine晶体的拉曼活性分子间和分子内振动的频率和能带结构的影响。压力和温度变化引起的分子间和分子内振动的拉曼频率，带宽和能带结构的变化表明（1）＃pi＃堆积层结构的剪切变形引起的位移相变可能在298 K下约1.7 GPa下发生（2）支持晶体中广泛网络结构的分子间氮-氯供体-受体吸引相互作用对完全对称的C-Cl拉伸振动具有直接影响。

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《Bulletin of the Chemical Society of Japan》 |2001年第7期|共7页
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Makiko Tanaka; Chinatu Kariu; Yoshio Suzuki; Yoshinori Nibu; Ryoichi Shimada; Hiroko Shimada;
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中图分类化学;化学工业;
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1. Pressure- and Temperature-Induced Phase Transition in 2,4,6-Trichloro-1,3,5-triazine Crystal [J] . Makiko Tanaka, Chinatu Kariu, Yoshio Suzuki, Bulletin of the Chemical Society of Japan . 2001,第7期

机译：2,4,6-三氯-1,3,5-三嗪晶体中压力和温度诱导的相变
2. Copper(II)-assisted thorough hydrolysis of 2,4,6-tris(2-pyridyl)1,3,5-triazine (TPTZ). Crystal structures of bis(2-pyridylcarboxylato)-copper(II) dihydrate and bis(2-pyridylcarbonyl)-amido-2,4,6-tris(2-pyridyl)-1,3,5-triazine-copper(II) dicyanamide h [J] . Zhao QH, Zhang MS, Fang RB Journal of structural chemistry . 2006,第4期

机译：铜（II）辅助彻底水解2,4,6-三（2-吡啶基）1,3,5-三嗪（TPTZ）。二水合双（2-吡啶基羧基）铜（II）和双（2-吡啶基羰基）-酰胺基-2,4,6-三（2-吡啶基）-1,3,5-三嗪-铜（II）的晶体结构双氰胺
3. Wet 2,4,6-trichloro-1,3,5-triazine(TCT)as an efficient catalyst for the synthesis of 2,4,6-triarylpyridines under solvent-free conditions [J] . Behrooz Maleki, Davood Azarifar, Hojat Veisi, 中国化学快报（英文版） . 2010,第011期

机译：湿式2,4,6-三氯-1,3,5-三嗪（TCT）作为无溶剂条件下合成2,4,6-三芳基吡啶的有效催化剂
4. The interaction of 2,4,6-trichloro-1,3,5-triazine with trinitromethane salts and adamanthyl alkanols [C] . Alexander A. Gidaspov, Vladimir V. Bakharev, Vladimir A. Zalomlenkov, Seminar on New Trends in Research of Energetic Materials . 2013

机译：2,4,6-三氯-1,3,5-三嗪与三硝基甲烷盐和金刚烷基烷醇的相互作用
5. Biological treatment of 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and the hydrolysates of RDX and HMX. [D] . Reinhart, George Albetz, III. 2001

机译：2,4,6-三硝基甲苯（TNT），六氢-1,3,5-三硝基-1,3,5-三嗪（RDX）和八氢-1,3,5,7-四硝基-1的生物处理， 3,5,7-四唑嗪（HMX），以及RDX和HMX的水解产物。
6. Cannabinoid Receptor 2 Signalling Bias Elicited by 2,4,6-Trisubstituted 1,3,5-Triazines [O] . Caitlin R. M. Oyagawa, Sara M. de la Harpe, Yurii Saroz, 2018

机译：2,4,6-三取代的1,3,5-三嗪引发的大麻受体2信号偏向
7. 2,4,6-Trichloro-1,3,5-triazine (TCT) mediated one pot direct synthesis of N-benzoylthioureas from carboxylic acids [O] . Somnath Gholap, Navanath Gunjal 2017

机译：2,4,6-三氯-1,3,5-三嗪（TCT）介导一锅直接合成羧酸中的N-苯甲酰基硫脲

Pressure- and Temperature-Induced Phase Transition in 2,4,6-Trichloro-1,3,5-triazine Crystal

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