Copper(II)-assisted thorough hydrolysis of 2,4,6-tris(2-pyridyl)1,3,5-triazine (TPTZ). Crystal structures of bis(2-pyridylcarboxylato)-copper(II) dihydrate and bis(2-pyridylcarbonyl)-amido-2,4,6-tris(2-pyridyl)-1,3,5-triazine-copper(II) dicyanamide h

Zhao QH; Zhang MS; Fang RB

首页> 外文期刊>Journal of structural chemistry >Copper(II)-assisted thorough hydrolysis of 2,4,6-tris(2-pyridyl)1,3,5-triazine (TPTZ). Crystal structures of bis(2-pyridylcarboxylato)-copper(II) dihydrate and bis(2-pyridylcarbonyl)-amido-2,4,6-tris(2-pyridyl)-1,3,5-triazine-copper(II) dicyanamide h

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Copper(II)-assisted thorough hydrolysis of 2,4,6-tris(2-pyridyl)1,3,5-triazine (TPTZ). Crystal structures of bis(2-pyridylcarboxylato)-copper(II) dihydrate and bis(2-pyridylcarbonyl)-amido-2,4,6-tris(2-pyridyl)-1,3,5-triazine-copper(II) dicyanamide h

机译：铜（II）辅助彻底水解2,4,6-三（2-吡啶基）1,3,5-三嗪（TPTZ）。二水合双（2-吡啶基羧基）铜（II）和双（2-吡啶基羰基）-酰胺基-2,4,6-三（2-吡啶基）-1,3,5-三嗪-铜（II）的晶体结构双氰胺

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2,4,6-Tris(2-pyridyl)-1,3,5-triazine (tptz) undergoes hydrolysis in the presence of copper(II) acetate affording bis(2-pyridylcarbonyl)amido-copper(II) and free 2-pyridylcarboxylic anion. Two compounds of formulas [Cu(NC5H4COO)(2)]center dot 2H(2)O (1) and [Cu(NC5H4CO)(2)N(tptz)](N(CN)(2))center dot 7H(2)O (2), where NC5H4COO- and (NC5H4CO)(2)N- are 2-pyridylcarboxylate and bis(2-pyridylcarbonyl)amido-anion, respectively, were obtained from methanol/ethanol solution of tptz with copper acetate; they were characterized by element analysis and single crystal X-ray diffraction method. Single crystal XRD analysis shows that in complex 1 coordination number around Cu atom is 4 with distorted square-planar coordination geometry and in complex 2 coordination number around Cu atom is 6 with distorted octahedral geometry. Crystal data for 1: a = 5.1359(10) angstrom, b = 7.6471(15) angstrom, c = 9.2303(18) angstrom, alpha = 74.90(3)degrees, beta = 84.36(3)degrees, gamma = 71.37(3)degrees, space group PI, crystal system triclinic, Z = 1, V = 331.6(1) angstrom(3), d(calc) = 1.721 g/cm(3). Crystallographic data for 2: space group C2/c, crystal system monoclinic, a = 23.976(5) angstrom, b = 15.465(3) angstrom, c = 18.649(4) angstrom, beta 92.66(3)degrees, V= 6907(2) angstrom(3), d(calc) = 1.0448 g/cm(3), Z = 4.

机译：2,4,6-三（2-吡啶基）-1,3,5-三嗪（tptz）在乙酸铜（II）的存在下进行水解，得到双（2-吡啶基羰基）氨基-铜（II）和游离2 -吡啶基羧基阴离子。式[Cu（NC5H4COO）（2）]中心点2H（2）O（1）和[Cu（NC5H4CO）（2）N（tptz）]（N（CN）（2））中心点7H（ 2）O（2），其中tptz与乙酸铜的甲醇/乙醇溶液制得NC5H4COO-和（NC5H4CO）（2）N-分别为2-吡啶基羧酸酯和双（2-吡啶基羰基）酰胺基阴离子。通过元素分析和单晶X射线衍射法对其进行了表征。单晶XRD分析表明，在Cu原子周围复杂的1配位数为4，方平面配位几何结构变形;在Cu原子周围复杂2的配位数为6，八面体几何变形。 1的晶体数据：a = 5.1359（10）埃，b = 7.6471（15）埃，c = 9.2303（18）埃，alpha = 74.90（3）度，beta = 84.36（3）度，γ= 71.37（3度，空间群PI，晶体系统三斜度，Z = 1，V = 331.6（1）埃（3），d（计算）= 1.721 g / cm（3）。 2的晶体学数据：空间群C2 / c，晶体系统单斜晶，a = 23.976（5）埃，b = 15.465（3）埃，c = 18.649（4）埃，beta 92.66（3）度，V = 6907（ 2）埃（3），d（计算）= 1.0448 g / cm（3），Z = 4。

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《Journal of structural chemistry》 |2006年第4期|共4页
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Zhao QH; Zhang MS; Fang RB;
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中图分类结构化学;
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2; 4; 6-tris(2-pyridyl)-1; 3; 5-triazine; copper complexes; crystal and molecular structure; CARBONYL-COMPLEXES; TRIAZINE RING; 2; 4; 6-TRIS(2-PYRIDYL)-1; 3; 5-TRIAZINE; 2; 4; 6-TRIS(2-PYRIMIDYL)-1; 3; 5-TRIAZINES; ATOM;

机译：2;4;6-三（2-吡啶基）-1;3;5-三嗪;铜配合物;晶体和分子结构;羰基络合物;三嗪环;2;4;6-TRIS（2-吡啶基）-1;3;5-三嗪;2;4;6-TRIS（2-吡啶基）-1;3;5-三嗪;原子;

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1. Copper(II)-assisted thorough hydrolysis of 2,4,6-tris(2-pyridyl)1,3,5-triazine (TPTZ). Crystal structures of bis(2-pyridylcarboxylato)-copper(II) dihydrate and bis(2-pyridylcarbonyl)-amido-2,4,6-tris(2-pyridyl)-1,3,5-triazine-copper(II) dicyanamide h [J] . Zhao QH, Zhang MS, Fang RB Journal of structural chemistry . 2006,第4期

机译：铜（II）辅助彻底水解2,4,6-三（2-吡啶基）1,3,5-三嗪（TPTZ）。二水合双（2-吡啶基羧基）铜（II）和双（2-吡啶基羰基）-酰胺基-2,4,6-三（2-吡啶基）-1,3,5-三嗪-铜（II）的晶体结构双氰胺
2. A mononuclear copper(II) complex based on the polypyridyl ligand 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz), [Cu(tptz) 2]~(2+): X-ray crystal structure, DNA binding and in vitro cell cytotoxicity [J] . Abdi K., Hadadzadeh H., Salimi M., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2012,第Null期

机译：基于多吡啶基配体2,4,6-三（2-吡啶基）-1,3,5-三嗪（tptz），[Cu（tptz）2]〜（2+）的单核铜（II）络合物：X射线晶体结构，DNA结合和体外细胞毒性
3. Synergistic extraction of lanthanoids with heterocyclic beta-ketoenols and 2,4,6-tri(2-pyridyl)-1,3,5-triazine,TPTZ Part II.Extraction of La(III),Eu(III) and Lu(III) with a bis(4-acyl-5-hydroxypyrazole) and TPTZ [J] . Elias Bou-Maroun, Anne Boos, Genevieve J.Goetz-Grandmont Separation and Purification Technology . 2007,第3期

机译：杂环β-酮烯醇和2,4,6-三（2-吡啶基）-1,3,5-三嗪协同萃取镧系元素，TPTZ部分II.La（III），Eu（III）和Lu（III）的提取）与双（4-酰基-5-羟基吡唑）和TPTZ
4. Blue phosphorescent organic light-emitting devices utilizing cesium–carbonate-doped 2,4,6-tris(2',4'-difluoro-1,1'-biphenyl-4-yl)-1,3,5-triazine [C] . James S. Swensen, James E. Rainbolt, Liang Wang, SPIE Conference on Organic Light Emitting Materials and Devices . 2011

机译：利用碳酸铯掺杂的2,4,6-Tris（2'，4'-二氟-1,1'-Biphenyl -4-基）-1,3,5-三嗪的蓝磷光有机发光器件
5. Relationship between ligand structure and reactivity for copper(II) complex mediated hydrolysis of phosphate diesters, carboxylic esters, and amides. Part~I. Hydrolysis of phosphate diesters promoted by copper(II) complexes. Part~II. Hydrolysis of carboxylic esters and amides catalyzed by copper(II) complexes. [D] . Jubian, Vrej. 1991

机译：铜（II）配合物介导的磷酸二酯，羧酸酯和酰胺水解的配体结构与反应性之间的关系。第一部分铜（II）配合物促进的磷酸二酯的水解。第二部分铜（II）配合物催化的羧酸酯和酰胺的水解。
6. 2,4,6-Tris(2,4-dimethylphenyl)-1,3,5-triazine [O] . Jin-Sheng Huang, Mao-Kui Li, Yang-Yi Yang, 2015

机译：2,4,6-Tris（2,4-二甲基基）-1,3,5-三嗪
7. Catalytic Flow-Injection Determination of Sub-ppb Copper(II) Using the Redox Reaction of Cysteine with Iron(III) in the Presence of 2,4,6-Tris(2-pyridyl)-1,3,5-triazine [O] . Jiatai WEI, Norio TESHIMA, Shinsuke OHNO, 2003

机译：在2,4,6-三（2-吡啶基）-1,3,5-三嗪存在下，使用铁（III）用铁（III）的半胱氨酸氧化还原反应催化流动喷射测定亚PPB铜（II）
8. Results of a Local Lymph Node Assay in Mice (LLNA/IMDS) with Toluene Diisocyanate based adduct in Organic Solvent (TDI Trimer) 1,3,5-Triazine- 2,4,6(1H,3H,5H)-trione, 1,3,5-tris(3-isocya natomethylphenyl). [R] . 2011

机译：基于甲苯二异氰酸酯的有机溶剂加成物（TDI三聚体）1,3,5-三嗪-2,4,6（1H，3H，5H） - 三酮，1小鼠局部淋巴结检测结果（LLNa / ImDs），3,5-三（3-isocya natomethylphenyl）。

Copper(II)-assisted thorough hydrolysis of 2,4,6-tris(2-pyridyl)1,3,5-triazine (TPTZ). Crystal structures of bis(2-pyridylcarboxylato)-copper(II) dihydrate and bis(2-pyridylcarbonyl)-amido-2,4,6-tris(2-pyridyl)-1,3,5-triazine-copper(II) dicyanamide h

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