A New Type of Uniformly Stacked Phase in Tetrathiapentalene-Based Organic Metals

Yoshimasa Bando; Takahiro Matsuzawa; Norihiro Takashita; Tadashi Kawamoto; Takehiko Mori

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A New Type of Uniformly Stacked Phase in Tetrathiapentalene-Based Organic Metals

机译：四硫杂戊烯基有机金属中新型均匀堆积相

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Two new organic electron donor molecules are synthesized on the basis of the ethylthio-substituted tetrathiapen-talenes with a methylenedithio or a 1,3-dithiane unit.These donors provide four isostructural radical-cation salts,which belong to a new crystal type with uniform stacks of the donor molecules.These salts show metallic conductivity down to low temperatures,linear temperature dependence of the thermoelectric power,and asymmetrical ESR lineshapes.The obtained uniform structure is compared with the previous uniform structure from the viewpoint of crystal packing.

机译：在具有亚甲二硫基或1,3-二硫杂环丁烷单元的乙硫基取代的四硫杂环戊二烯基础上合成了两个新的有机电子给体分子，这些给体提供了四种同结构的自由基阳离子盐，属于一种具有均匀结构的新型晶体这些盐在低温下显示出金属导电性，热电的线性温度依赖性以及不对称的ESR线形。从晶体堆积的角度，将所得的均匀结构与以前的均匀结构进行了比较。

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《Bulletin of the Chemical Society of Japan》 |2005年第8期|共8页
作者
Yoshimasa Bando; Takahiro Matsuzawa; Norihiro Takashita; Tadashi Kawamoto; Takehiko Mori;
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正文语种 eng
中图分类化学;
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1. A New Type of Uniformly Stacked Phase in Tetrathiapentalene-Based Organic Metals [J] . Yoshimasa Bando, Takahiro Matsuzawa, Norihiro Takashita, Bulletin of the Chemical Society of Japan . 2005,第8期

机译：四硫杂戊烯基有机金属中新型均匀堆积相
2. Metal-Insulator Transition of the New One-Dimensional Organic Conductors with Complete Uniform Stacks: (DMEDO-TTF)(2)X (X = ClO4 and BF4) [J] . Kumeta Shohei, Kawamoto Tadashi, Shirahata Takashi, Journal of the Physical Society of Japan . 2016,第9期

机译：具有完全均匀堆叠的新型一维有机导体的金属-绝缘体过渡：（DMEDO-TTF）（2）X（X = ClO4和BF4）
3. A 2 [16] B 4 [12] of the Friauf Families Mg 2Cu 4 and Mg 2Zn 4]]> [J] . G. D. Ilyushin Crystallography reports . 2018,第4期

机译：<！[CDATA [CONTRICAL COMPERIC化合物的对称性和拓扑代码金属间化合物的自组装<重点类型=“斜体”> A <堆栈> <下标> 2 [16] <重点类型=“斜体”> b 4 [12] friauf families mg < 下标> 2 CU <下标> 4 和mg 2 zn 4 ]]>
4. EVALUATION ON THE POTENTIAL WITH CHANNEL-TYPE AND CAGE-TYPE METAL-ORGANIC FRAMEWORKS AS ABSORBENTS IN SOLID-PHASE MICROEXTRACTION [C] . Hsi-Ya Huang, Stephen Lirio, Yung-Han Shih ACS National Meeting Exhibition . 2015

机译：渠道型和笼式金属 - 有机框架的潜力评价为固相微萃取中的吸收剂
5. Herringbone and pi-stacked phases of pentacene thin films grown on metal surfaces. [D] . Kang, Joo Hyun. 2005

机译：在金属表面上生长的并五苯薄膜的人字形和π堆积相。
6. Data in support of crystal structures of highly-ordered long-period stacking-ordered phases with 18R 14H and 10H-type stacking sequences in the Mg–Zn–Y system [O] . Kyosuke Kishida, Kaito Nagai, Akihide Matsumoto, 2015

机译：Mg–Zn–Y系统中支持18R14H和10H型堆积序列的高序长周期堆积有序相的晶体结构的数据
7. Optimising uniformity of InAs/(InGaAs)/GaAs quantum dots grown by metal organic vapor phase epitaxy [O] . Höglund, Linda, Petrini, E., Asplund, C., 2006

机译：优化金属有机气相外延生长的InAs /（InGaAs）/ GaAs量子点的均匀性
8. P-type and N-type doping in GaSb and Ga(sub 0.8)In(sub 0.2)Sb layers grown by metalorganic vapor phase epitaxy [R] . Ehsani, H., Bhat, I., Hitchcock, C., 1998

机译：通过金属有机气相外延生长的Gasb和Ga（sub 0.8）In（sub 0.2）sb层中的p型和N型掺杂

A New Type of Uniformly Stacked Phase in Tetrathiapentalene-Based Organic Metals

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