Tetramethylated Resorcin[4]arene-Based Molecular Capsules Incorporating a Tetraethylammonium Ion through Cation-pi Interactions

Katsuyuki Aoki; Toshiki Nagae; Sumio Yamaguchi; Ikuhide Fujisawa

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Tetramethylated Resorcin[4]arene-Based Molecular Capsules Incorporating a Tetraethylammonium Ion through Cation-pi Interactions

机译：四甲基间苯二酚[4]芳烃基分子胶囊通过阳离子-π相互作用掺入四乙基铵离子

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摘要

Tetramethylated resorcin[4]arene self-assembles to form molecular capsules incorporating a tetraethylammo-nium ion within the cavity through cation-pi interactions.Two"head-to-head"arranged substructures are staggered with each other so as to participate in methyl-hydroxy van der Waals interactions between pairing substructures.The tetraethylammonium ion is oriented in a vertical or horizontal fashion.

机译：四甲基间苯二酚[4]芳烃通过阳离子-pi相互作用自组装形成在腔内掺入四乙基铵离子的分子胶囊。两个“头对头”排列的子结构相互交错，从而参与甲基-配对亚结构之间的羟基范德华相互作用。四乙铵离子以垂直或水平方式取向。

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《Bulletin of the Chemical Society of Japan》 |2005年第11期|共3页
作者
Katsuyuki Aoki; Toshiki Nagae; Sumio Yamaguchi; Ikuhide Fujisawa;
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1. Tetramethylated Resorcin[4]arene-Based Molecular Capsules Incorporating a Tetraethylammonium Ion through Cation-pi Interactions [J] . Katsuyuki Aoki, Toshiki Nagae, Sumio Yamaguchi, Bulletin of the Chemical Society of Japan . 2005,第11期

机译：四甲基间苯二酚[4]芳烃基分子胶囊通过阳离子-π相互作用掺入四乙基铵离子
2. Self-assembly of tetramethylated resorcin[4]arene to form molecular capsules incorporating methanol, ethanol, and imidazole: A comparison with the unsubstituted resorcin[4]arene system [J] . Aoki K, Nagae T, Matsubara R, Chemistry Letters . 2004,第10期

机译：四甲基间苯二酚[4]芳烃的自组装形成包含甲醇，乙醇和咪唑的分子胶囊：与未取代的间苯二酚[4]芳烃体系的比较
3. Versatile self-assembled molecular capsule formation of a resorcin[4]arene-based benzamidoiminocavitand [J] . Yeon Sil Park, Juwan Park, Kyungsoo Paek Chemical Communications . 2013,第56期

机译：间苯二酚[4]芳烃基苯甲酰胺基氨基苯甲酸酯的多功能自组装分子胶囊形成
4. The role of tryptophan cation-pi interactions onammonia transport through the AmtBammonia channel [C] . William E.C. Harries, Shahram Khademi, Robert M. Strou International Study Group for Tryptophan Research . 2007

机译：色氨酸阳离子-PI相互作用onammonia通过Amtbammonia渠道的作用
5. Supramolecular interactions from small-molecule selectivity to molecular capsules. [D] . Rajbanshi, Arbin. 2010

机译：从小分子选择性到分子胶囊的超分子相互作用。
6. Cation-pi bonding and amino-aromatic interactions in the biomolecular recognition of substituted ammonium ligands. [O] . N S Scrutton, A R Raine 1996

机译：在取代铵配体的生物分子识别中的阳离子-π键和氨基-芳族相互作用。
7. Cation-pi interactions stabilize the structure of the antimicrobial peptide indolicidin near membranes: molecular dynamics simulations [O] . Khandelia, Himanshu, Kaznessis, Yiannis N 2007

机译：阳离子-π相互作用可稳定膜附近抗菌肽吲哚美定的结构：分子动力学模拟

Tetramethylated Resorcin[4]arene-Based Molecular Capsules Incorporating a Tetraethylammonium Ion through Cation-pi Interactions

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