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首页> 外文期刊>Bulletin of the Chemical Society of Japan >Microsphere vs. Microbelt Morphology of Ionic Palladium(II) Complexes
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Microsphere vs. Microbelt Morphology of Ionic Palladium(II) Complexes

机译:离子钯(II)配合物的微球与微带形态

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A series of palladium(II) complexes containing bis[(4-isonicotinoyloxy)plienyl]sulfide (L), [Pd-II(L)(tmen)](2)X-4 (tmen = N,N,N',N'-tetramethylethane-1,2-diamine; X = NO3 and ClO4) were prepared and characterized. Reaction of [Pd(tmen)](NO3)(2) with L in a mixture of water and acetone affords microspheres whereas reaction of [Pd(tmen)](ClO4)(2) with L produces microbelts. The Solubility of the products is a significant factor for the formation of morphology. The spherical sizes can be controlled by the evaporation rate of solvents. An array of approximate to 300 nm and approximate to 4 mu m bimodal spheres wits carried out via sonication.
机译:一系列含有双[(4-异烟酰氧基)联苯基]硫化物(L),[Pd-II(L)(tmen)](2)X-4(tmen = N,N,N',制备并表征了N'-四甲基乙烷-1,2-二胺; X = NO 3和ClO 4。 [Pd(tmen)](NO3)(2)与L在水和丙酮的混合物中反应生成微球,而[Pd(tmen)](ClO4)(2)与L的反应生成微带。产品的溶解度是形成形态的重要因素。球形尺寸可以通过溶剂的蒸发速率来控制。通过超声处理,形成了大约300 nm和大约4μm的双峰球阵列。

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