Preparation and Crystal Structures of 1:1 Adducts of Lanthanide Nitrate with Tri(2-pyridyl)amine

Noriharu Nagao; Keita Egashira; Daisuke Mogi

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Preparation and Crystal Structures of 1:1 Adducts of Lanthanide Nitrate with Tri(2-pyridyl)amine

机译：硝酸镧与三（2-吡啶基）胺1：1加合物的制备及晶体结构

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A series of 1:1 adducts between late-lanthanide nitrate and tri(2-pyridyl)amine(tpa),fLn(NO_3)_3(EtOH)_3](center dot)(tpa)(center dot)0.5EtOH(Ln~3+=Er~3+,Yb~3+,and Lu~3+)was synthesized.These 1:1 adducts possess similar crystal structures,in which the tpa molecules interact face-to-face with the triangular base of [Ln(NO_3)_3(EtOH)_3] through three hydrogen bonds.

机译：硝酸镧系元素与三（2-吡啶基）胺（tpa），fLn（NO_3）_3（EtOH）_3]（中心点）（tpa）（中心点）0.5EtOH（Ln〜合成了3 + = Er〜3 +，Yb〜3 +和Lu〜3 +）。这些1：1加合物具有相似的晶体结构，其中tpa分子与[Ln （NO_3）_3（EtOH）_3]通过三个氢键。

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《Bulletin of the Chemical Society of Japan》 |2004年第6期|共2页
作者
Noriharu Nagao; Keita Egashira; Daisuke Mogi;
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1. Preparation and Crystal Structures of 1:1 Adducts of Lanthanide Nitrate with Tri(2-pyridyl)amine [J] . Noriharu Nagao, Keita Egashira, Daisuke Mogi Bulletin of the Chemical Society of Japan . 2004,第6期

机译：硝酸镧与三（2-吡啶基）胺1：1加合物的制备及晶体结构
2. Preparation and characterization of lanthanide(III) complexes with polybenzimidazole ligands. Crystal structure of bis[tris(N-methyl-1-benzimidazol-2-yl)amine]lanthanum(III) perchlorate monoacetonitrile solvate [J] . Liu JC., Wang LF., Zhuang JH., Acta Chemica Scandinavica . 1999,第2期

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Preparation and Crystal Structures of 1:1 Adducts of Lanthanide Nitrate with Tri(2-pyridyl)amine

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