...
首页> 外文期刊>The Journal of Chemical Thermodynamics >(Liquid plus liquid) equilibria of three ternary systems: (heptane plus benzene plus N-formylmorpholine), (heptane plus toluene plus N-formylmorpholine), (heptane plus xylene plus N-formylmorpholine) from T = (298.15 to 353.15) K
【24h】

(Liquid plus liquid) equilibria of three ternary systems: (heptane plus benzene plus N-formylmorpholine), (heptane plus toluene plus N-formylmorpholine), (heptane plus xylene plus N-formylmorpholine) from T = (298.15 to 353.15) K

机译:三种三元体系的(液体加液体)平衡:(庚烷+苯+ N-甲酰基吗啉),(庚烷+甲苯+ N-甲酰基吗啉),(庚烷+二甲苯+ N-甲酰基吗啉)从T =(298.15至353.15)K

获取原文
获取原文并翻译 | 示例
           

摘要

(Liquid + liquid) equilibrium (LLE) data for ternary systems: (heptane + benzene + N-formylmorpholine), (heptane + toluene + N-formylmorpholine), and (heptane + xylene + N-formylmorpholine) have been determined experimentally at temperatures ranging from 298.15 K to 353.15 K. Complete phase diagrams were obtained by determining solubility and tie-line data. Tie-line compositions were correlated by Othmer-Tobias and Bachman methods. The universal quasichemical activity coefficient (UNIQUAC) and the non-random two liquids equation (NRTL) were used to predict the phase equilibrium in the system using the interaction parameters determined from experimental data. It is found that UNIQUAC and NRTL used for LLE could provide a good correlation. Distribution coefficients, separation factors, and selectivity were evaluated for the immiscibility region. (c) 2007 Elsevier Ltd. All rights reserved.
机译:三元体系的(液体+液体)平衡(LLE)数据:(庚烷+苯+ N-甲酰基吗啉),(庚烷+甲苯+ N-甲酰基吗啉)和(庚烷+二甲苯+ N-甲酰基吗啉)已在温度下通过实验确定范围从298.15 K到353.15K。通过确定溶解度和联系数据获得了完整的相图。联络线组成通过Othmer-Tobias和Bachman方法进行关联。利用从实验数据确定的相互作用参数,使用通用准化学活度系数(UNIQUAC)和非随机两种液体方程(NRTL)来预测系统中的相平衡。发现用于LEE的UNIQUAC和NRTL可以提供良好的相关性。评估了不混溶区域的分布系数,分离因子和选择性。 (c)2007 Elsevier Ltd.保留所有权利。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号