Reactions of 2,3-Dioxopyrrolo[2,1-a]isoquinolines with Active N-Nucleophiles

N. N. Polygalova; A. G. Mikhailovskii

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Reactions of 2,3-Dioxopyrrolo[2,1-a]isoquinolines with Active N-Nucleophiles

机译：2,3-二氧杂吡咯并[2,1-a]异喹啉与活性N-亲核试剂的反应

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摘要

It is shown that 2,3-dioxopyrrolo[2,1-a]isoquinolines react readily with aliphatic diamines and hydroxyamine with opening of the dioxopyrrole ring and formation of the corresponding bisenaminoketoamides and hydroxamic acids. Reaction with the thiosemicarbazide and hydrazides of aromatic acids proceeds without opening of the pyrrole ring at the ketone carbonyl. Derivatives of hexahydropyridazine are formed when compounds with carboxyethyl groups at position 1 react with hydrazine.

机译：结果表明2,3-二氧杂吡咯并[2,1-a]异喹啉容易与脂肪族二胺和羟胺反应，并打开二氧杂吡咯环并形成相应的双亚氨基氨基酰胺和异羟肟酸。与芳族酸的硫代氨基甲酰肼和酰肼的反应在酮羰基上不打开吡咯环的情况下进行。当在位置1具有羧基乙基的化合物与肼反应时，会形成六氢哒嗪的衍生物。

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来源
《Chemistry of heterocyclic compounds》 |2005年第9期|共5页
作者
N. N. Polygalova; A. G. Mikhailovskii;
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正文语种 eng
中图分类杂环化合物;
关键词
aliphatic diamines; bisenaminoketoamides; hydrazides of aromatic acids; hydrazine; hydroxamic acids; hydroxylamine; 5; 5-dialkyl-2; 3-dioxopyrrolo2; 1-aisoquinolines; perhydropyridazine; thiosemicarbazide;

机译：脂族二胺;双烯氨基酮酰胺;芳香酸的酰肼;肼;异羟肟酸;羟胺;5;5-二烷基-2;3-二氧代吡咯并[2;1-a]异喹啉;全氢哒嗪;硫代氨基脲;

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专利

1. Reactions of 2,3-Dioxopyrrolo[2,1-a]isoquinolines with Active N-Nucleophiles [J] . N. N. Polygalova, A. G. Mikhailovskii Chemistry of heterocyclic compounds . 2005,第9期

机译：2,3-二氧杂吡咯并[2,1-a]异喹啉与活性N-亲核试剂的反应
2. Reactions of 2,3-Dioxopyrrolo[2,1-a]isoquinolines with Ammonia and Aliphatic Amines [J] . A. G. Mikhailovskii, N. N. Polygalova, T. S. Turova, Chemistry of heterocyclic compounds . 2004,第9期

机译：2,3-二氧杂吡咯并[2,1-a]异喹啉与氨和脂肪胺的反应
3. Reaction of 2,3-Dioxopyrrolo-[2,1-a]isoquinolines with Aromatic and Secondary Aliphatic Amines [J] . N. N. Polygalova, A. G. Mikhailovskii Chemistry of heterocyclic compounds . 2005,第9期

机译：2,3-二氧杂吡咯并[2,1-a]异喹啉与芳香和仲脂肪胺的反应
4. Synthesis and reactions of 2,3-diaryltetrazolium mesoionic compounds [C] . Mirai Nakata, Tsunehisa Hirashita 日本化学会春季年会講演予稿集 . 2018

机译：2,3-二芳基三唑鎓中碘化合物的合成与反应
5. Synthesis of conjugates of L-fucose and ortho-carborane as potential agents for boron neutron capture therapy, and, Synthesis of 2,3-dideoxy-2,3-methanoribofuranoside glycosyl donors and a study of their use in stereocontrolled glycosylation reactions. [D] . Basak, Prakriti. 2003

机译：合成L-岩藻糖和邻位碳硼烷作为硼中子俘获治疗的潜在药物，以及2,3-二脱氧-2,3-甲基呋喃呋喃糖苷糖基供体的合成及其在立体控制糖基化反应中的应用研究。
6. Dimethyl 3-(cyclopropylcarbonyl)pyrrolo[2,1-a]isoquinoline-1,2-dicarboxylate [O] . Honglong Xing, Fan Tang, Wei Wang 2015

机译：3-（环丙基丙基碳烷基）吡咯并[2,1-a]异喹啉-1,2-二羧酸二甲酯
7. Reaction of 2,3-dioxopyrrolo2,1-aisoquinolines with naphthalene-2,3-diamine [O] . O. V. Surikova, A. G. Mikhailovskii, M. I. Vakhrin 2011

机译：2,3-二氧吡咯的反应2,1-A异喹啉与萘-2,3-二胺
8. Synthesis of Heterocycles: Indolo(2,1-a)isoquinolines, Renewables, and Aptamer Ligands for Cellular Imaging. [R] . Beasley, J. 2013

机译：杂环的合成：用于细胞成像的Indolo（2,1-a）异喹啉，可再生物和适体配体。

Reactions of 2,3-Dioxopyrrolo[2,1-a]isoquinolines with Active N-Nucleophiles

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