The transition dipole moment function of the chlorine E0(g)(+)(P-3(2))-B-3 Pi 0(u)(+) system

Bibinov NK.; Fateev AA.; Kokh DB.; Lugovoj EV.; Ottinger C. Pravilov AM.; Davydov VK.

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The transition dipole moment function of the chlorine E0(g)(+)(P-3(2))-B-3 Pi 0(u)(+) system

机译：氯E0（g）（+）（P-3（2））-B-3 Pi 0（u）（+）系统的跃迁偶极矩函数

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Specific rovibrational levels of the E0(g)(+) ion-pair state of Cl-2 have been laser excited by optical-optical double resonance (OODR) via the B0(u)(+) state. A two-color, single-laser visible+ultraviolet (VIS + UV) scheme was used, where the UV radiation was derived by second-harmonic generation from the VIS laser output. Spectrally resolved emission at 240-265 nm was observed. The E0(g)(+) --> BOu+ spectra exhibited both discrete and continuous (Condon oscillation) parts, from which the E --> B electronic transition moment curve M-e(R) was derived. It is compared with corresponding results on ion-pair states of I-2. (C) 1998 American Institute of Physics. [S0021-9606(98)00648-5]. [References: 37]

机译：Cl-2的E0（g）（+）离子对状态的特定旋转振动能级通过B0（u）（+）状态通过光学双共振（OODR）进行激光激发。使用了两种颜色的单激光可见光+紫外线（VIS + UV）方案，其中UV辐射是通过VIS激光输出的二次谐波产生而得出的。在240-265nm处观察到光谱分辨的发射。 E0（g）（+）-> BOu +光谱同时显示出离散和连续（康登振荡）部分，从中可以得出E-> B电子跃迁矩曲线M-e（R）。将其与I-2离子对状态的相应结果进行比较。（C）1998美国物理研究所。 [S0021-9606（98）00648-5]。 [参考：37]

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《The Journal of Chemical Physics》 |1998年第24期|共9页
作者
Bibinov NK.; Fateev AA.; Kokh DB.; Lugovoj EV.; Ottinger C. Pravilov AM.; Davydov VK.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Optical double-resonance; Ion-pair states; Franck-condon factors; 1st observation; Band systems; Spectroscopy; Cl2; Fluorescence; Lifetimes; Emission;

机译：光学双共振;离子对态;弗兰克-康登因子;第一次观察;能带系统;光谱学;Cl2;荧光;寿命;发射;

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机译：氯E0（g）（+）（P-3（2））-B-3 Pi 0（u）（+）系统的跃迁偶极矩函数
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The transition dipole moment function of the chlorine E0(g)(+)(P-3(2))-B-3 Pi 0(u)(+) system

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