OSCILLATORY SURFACE FORCES - A TEST OF THE SUPERPOSITION APPROXIMATION

Frink LJD.; Vanswol F.

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OSCILLATORY SURFACE FORCES - A TEST OF THE SUPERPOSITION APPROXIMATION

机译：振荡表面力-叠加逼近的试验

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We report on the density functional theory calculations of electrolyte solutions confined between charged plates. Experiments with the surface forces apparatus have shown that for charged cylinders in simple solvents the surface force is oscillatory at short range. It has been suggested that the total force be considered a superposition of the electrostatic repulsion, the solvation force of a pure solvent, and the van der Waals attraction. In this paper we use the Rosenfeld-Kierlik-Rosinberg (RKR) functional to study a three-component electrolyte solution and explicitly test the superposition approximation, We find that the superposition on approximation is a good approximation when the surface charge is low and the salt concentration is high. We also find that a three-component electrolyte can display short-range equilibrium separations in the absence of van der Waals interactions. (C) 1996 American Institute of Physics. [References: 25]

机译：我们报告了封闭的带电板之间的电解质溶液的密度泛函理论计算。用表面力装置进行的实验表明，对于装满溶剂的圆柱体，在简单溶剂中，表面力在短范围内会产生振荡。已经提出总力被认为是静电斥力，纯溶剂的溶剂化力和范德华吸引力的叠加。在本文中，我们使用Rosenfeld-Kierlik-Rosinberg（RKR）函数研究三组分电解质溶液，并明确测试了叠加近似，我们发现，当表面电荷较低且盐分较低时，近似的叠加是良好的近似浓度高。我们还发现，在没有范德华相互作用的情况下，三组分电解质可以显示短程平衡分离。（C）1996年美国物理研究所。 [参考：25]

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《The Journal of Chemical Physics》 |1996年第7期|共7页
作者
Frink LJD.; Vanswol F.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Density-functional theory; Electrical double-layer; Dna double helices; Hard-sphere fluid; Solvation forces; Polar liquid; Model; Adsorption;

机译：密度泛函理论;电子双层;Dna双螺旋;硬球流体;溶剂化力;极性液体;模型;吸附;

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1. OSCILLATORY SURFACE FORCES - A TEST OF THE SUPERPOSITION APPROXIMATION [J] . Frink LJD., Vanswol F. The Journal of Chemical Physics . 1996,第7期

机译：振荡表面力-叠加逼近的试验
2. Ternary Fluid Mixture Confined between Surfaces: Surface-induced Phase Transition and Long-range Oscillatory Forces [J] . Soumi Banerjee, Pieter Mulder, J. Mieke Kleijn Chemistry Letters . 2012,第10期

机译：限制在表面之间的三元流体混合物：表面诱导的相变和远距离振荡力
3. Oscillatory Forces of Nanoparticle Suspensions Confined between Rough Surfaces Modified with Polyelectrolytes via the Layer-by-Layer Technique [J] . Yan Zeng and Regine von Klitzing Langmuir . 2012,第15期

机译：纳米粒子悬浮液的振荡力通过逐层技术限制在聚电解质修饰的粗糙表面之间
4. IMPROVING ROBOTIZED NON DESTRUCTIVE TESTING FOR LARGE PARTS WITH LOCAL SURFACE APPROXIMATION AND FORCE CONTROL SCHEME [C] . O. Patrouix, S. Bottecchia, J. Canou International Conference on Composite Materials . 2013

机译：具有局部表面近似和力控制方案的大型零件的机器化无损检测
5. Design, fabrication and test of surface tension-driven microboats and thermally oscillatory bubble-propelled microsubmarines. [D] . Qiao, Lei. 2013

机译：表面张力驱动的微艇和热振荡气泡推进式微型潜艇的设计，制造和测试。
6. Polynomial force approximations and multifrequency atomic force microscopy [O] . Daniel Platz, Daniel Forchheimer, Erik A Tholén, 2013

机译：多项式力近似和多频原子力显微镜
7. The oceans mediate the response of global climate to natural and anthropogenic forcings. Yet for the past 2,000 years — a key interval for understanding the present and future climate response to these forcings — global sea surface temperature changes and the underlying driving mechanisms are poorly constrained. Here we present a global synthesis of sea surface temperatures for the Common Era (ce) derived from 57 individual marine reconstructions that meet strict quality control criteria. We observe a cooling trend from 1 to 1800 ce that is robust against explicit tests for potential biases in the reconstructions. Between 801 and 1800 ce, the surface cooling trend is qualitatively consistent with an independent synthesis of terrestrial temperature reconstructions, and with a sea surface temperature composite derived from an ensemble of climate model simulations using best estimates of past external radiative forcings. Climate simulations using single and cumulative forcings suggest that the ocean surface cooling trend from 801 to 1800 ce is not primarily a response to orbital forcing but arises from a high frequency of explosive volcanism. Our results show that repeated clusters of volcanic eruptions can induce a net negative radiative forcing that results in a centennial and global scale cooling trend via a decline in mixed-layer oceanic heat content. [O] . McGregor, Helen V., Evans, Michael N., Goosse, Hugues, 2015

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8. Seakeeping Characteristics of the XR-5, A High Length-Beam Ratio Manned Surface Effect Testcraft:III. Results of Random Wave Experiments Investigation of Linear Superposition for Ship Motions and Trim and Draft in Random Waves, [R] . ricci,joseph j. magnuson,allen h. 1976

机译：XR-5的耐波特性，高长度比率载人表面效应试验台：III。随机波实验研究船舶运动线性叠加和随机波浪中的修剪和拔模，

OSCILLATORY SURFACE FORCES - A TEST OF THE SUPERPOSITION APPROXIMATION

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